[6Li]phenyllithium

Base Information

• Chemical Name: [6Li]phenyllithium
• CAS No.: 92382-42-8
• Molecular Formula: C₆H₅Li
• Molecular Weight: 83.1057
• Mol file: 92382-42-8.mol

Synonyms:[6Li]phenyllithium

Chemical Property of [6Li]phenyllithium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [6Li]phenyllithium

There total 2 articles about [6Li]phenyllithium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

bromobenzene (108-86-1,52753-63-6) → [6Li]phenyllithium (92382-42-8)

Guidance literature:

With sec.-butyllithium; In pentane; for 24h;

DOI:10.1021/ja00128a020

Reference yield:

iodobenzene (591-50-4) + [(6)Li]-n-butyllithium (20535-67-5) → [6Li]phenyllithium (92382-42-8)

Guidance literature:

In pentane; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1021/om300352p

Reference yield:

[6Li]phenyllithium (92382-42-8) + copper(I) bromide (7787-70-4) → diphenylcopperlithium-6 (113811-10-2)

Guidance literature:

In further solvent(s); byproducts: LiBr; addn. of cold ( 0°C) soln. of Ph(6)Li in DMS to cold soln. of CuBr in DMS; soln. brought to 0°C; pptn. of LiBr;;

DOI:10.1021/ja00219a057

upstream raw materials:

bromobenzene

iodobenzene

[⁽⁶⁾Li]-n-butyllithium

Downstream raw materials:

diphenylcopperlithium-6

2⁽⁶⁾Li⁽¹⁺⁾*Cu⁽¹⁺⁾*I^(1-)*2C₆H₅^(1-)=(C₆H₅)2CuI⁽⁶⁾Li₂