2-tert-Butyldiphenylsilyl-2-phenylethanal

Base Information

Chemical Name:2-tert-Butyldiphenylsilyl-2-phenylethanal
CAS No.:263248-72-2
Molecular Formula:C₂₄H₂₆OSi
Molecular Weight:358.555
Hs Code.:

Synonyms:2-tert-Butyldiphenylsilyl-2-phenylethanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-tert-Butyldiphenylsilyl-2-phenylethanal

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Technology Process of 2-tert-Butyldiphenylsilyl-2-phenylethanal

There total 3 articles about 2-tert-Butyldiphenylsilyl-2-phenylethanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: trans-β-phenyl-α-tert-butyldiphenylsilylepoxide

: 263248-72-2
2-tert-Butyldiphenylsilyl-2-phenylethanal

Guidance literature:: With sulfuric acid; In tetrahydrofuran; at 65 ℃; for 5h;
DOI:10.1055/s-2000-6409

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 263248-72-2
2-tert-Butyldiphenylsilyl-2-phenylethanal

Guidance literature:: Multi-step reaction with 3 steps

1.1: Li / tetrahydrofuran / 4 h / 0 °C

1.2: CuCN; BuLi / 0.75 h / 0 °C

1.3: 82 percent / tetrahydrofuran / 1 h / -78 °C

2.1: 95 percent / MCPBA; NaHCO₃ / CH₂Cl₂ / 24 h / 60 °C

3.1: 95 percent / H₂SO₄ / tetrahydrofuran / 5 h / 65 °C

With sulfuric acid; lithium; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; 1.1: Metallation / 1.2: Transmetallation / 1.3: Addition / 2.1: Epoxidation / 3.1: Rearrangement;
DOI:10.1055/s-2000-6409

Reference yield:

: 167865-53-4
(E)-1-tert-butyl(diphenyl)silyl-2-phenylethene

: 263248-72-2
2-tert-Butyldiphenylsilyl-2-phenylethanal

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / MCPBA; NaHCO₃ / CH₂Cl₂ / 24 h / 60 °C

2: 95 percent / H₂SO₄ / tetrahydrofuran / 5 h / 65 °C

With sulfuric acid; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; 1: Epoxidation / 2: Rearrangement;
DOI:10.1055/s-2000-6409