tricarbonyl bis(tri-p-tolylphosphine) iron

Base Information

• Chemical Name: tricarbonyl bis(tri-p-tolylphosphine) iron
• CAS No.: 52500-74-0
• Molecular Formula: C₄₅H₄₂FeO₃P₂
• Molecular Weight: 748.621
• Mol file: 52500-74-0.mol

Synonyms:tricarbonyl bis(tri-p-tolylphosphine) iron

Chemical Property of tricarbonyl bis(tri-p-tolylphosphine) iron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tricarbonyl bis(tri-p-tolylphosphine) iron

There total 5 articles about tricarbonyl bis(tri-p-tolylphosphine) iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

K(1+)*H(1+)*Fe(CO)4(2-)=KHFe(CO)4 + Tri(p-tolyl)phosphine (1038-95-5,218281-19-7) → tricarbonyl bis(tri-p-tolylphosphine) iron (52500-74-0)

Guidance literature:

In ethanol; other Radiation; under N2; EtOH soln. of KHFe(CO)4 added to P(C6H5CH3)3; heated in microwave reactor (150 W, 5 min, 100°C, max T=112°C, max P=50 psi); cooled to room temp.; ppt. collected by suction filtration; washed with H2O and EtOH; dried;

DOI:10.1021/om900821c

Reference yield: 43.0%

diiron nonacarbonyl (15321-51-4) + N-sulphinyl-p-bromoaniline (26516-62-1,52866-94-1) + Tri(p-tolyl)phosphine (1038-95-5,218281-19-7) → iron pentacarbonyl (13463-40-6,37220-42-1) + tricarbonyl bis(tri-p-tolylphosphine) iron (52500-74-0) + (CO)4FeP(C6H4CH3-p)3 (52278-75-8,52553-46-5) + [Fe(P(4-MeC6H4)3)2(CO)2(4-BrC6H4NSO)] (85134-89-0)

Guidance literature:

In tetrahydrofuran; under N2, mixt. of Fe-complex, 4-BrC6H4NSO and (4-MeC6H4)3P (molar ratio 1:1:2) in THF were stirred for 1-4 h at room temp.; filtered, recrystd. from ether-MeOH or CH2Cl2-hexane; elem. anal.;

Reference yield: 40.0%

diiron nonacarbonyl (15321-51-4) + 4-ClC6H4NSO (13165-68-9,52867-11-5) + Tri(p-tolyl)phosphine (1038-95-5,218281-19-7) → iron pentacarbonyl (13463-40-6,37220-42-1) + tricarbonyl bis(tri-p-tolylphosphine) iron (52500-74-0) + (CO)4FeP(C6H4CH3-p)3 (52278-75-8,52553-46-5) + [Fe(P(4-MeC6H4)3)2(CO)2(4-ClC6H4NSO)] (85134-88-9)

Guidance literature:

In tetrahydrofuran; under N2, mixt. of Fe-complex, 4-ClC6H4NSO and (4-MeC6H4)3P (molar ratio 1:1:2) in THF were stirred for 1-4 h at room temp.; filtered, recrystd. from ether-MeOH or CH2Cl2-hexane; elem. anal.;

upstream raw materials:

triiron dodecarbonyl

Tri(p-tolyl)phosphine

diiron nonacarbonyl

N-sulphinyl-p-bromoaniline

Downstream raw materials:

iron pentacarbonyl

(CO)4FeP(C₆H₄CH₃-p)3

Tri(p-tolyl)phosphine