(S)-(+)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol acetate methanesulfonate

Base Information

Chemical Name:(S)-(+)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol acetate methanesulfonate
CAS No.:132554-00-8
Molecular Formula:C₁₄H₁₉BrO₅S
Molecular Weight:379.272
Hs Code.:

Synonyms:(S)-(+)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol acetate methanesulfonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-(+)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol acetate methanesulfonate

Chemical Property:

Purity/Quality:

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Technology Process of (S)-(+)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol acetate methanesulfonate

There total 8 articles about (S)-(+)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol acetate methanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 127633-44-7
(R)-(+)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol monoacetate

: 124-63-0
methanesulfonyl chloride

: 132554-00-8
(S)-(+)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol acetate methanesulfonate

: 127633-47-0
(R)-(+)-β-(Azidomethyl)-4-bromobenzenebutanol

Guidance literature:: With hydrogenchloride; triethylamine; In dichloromethane;

Reference yield:

: 124-63-0
methanesulfonyl chloride

: (RS)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol monoacetate

: 132554-00-8
(S)-(+)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol acetate methanesulfonate

: (R)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol acetate methanesulfonate

Guidance literature:: With triethylamine; In chloroform; at 0 ℃; for 0.25h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1021/jo00102a031

Reference yield:

: 4654-39-1
4-bromophenethanol

: 132554-00-8
(S)-(+)-2-<2-(4-Bromophenyl)ethyl>-1,3-propanediol acetate methanesulfonate

Guidance literature:: Multi-step reaction with 5 steps

1: Et₃N

2: 90 percent / NaH

3: 75 percent / LiAlH₄ / diethyl ether

4: 90 percent / with porcine pancreatic lipase (PPL, Sigma type II, no. 3126)

5: Et₃N

With lithium aluminium tetrahydride; sodium hydride; triethylamine; In diethyl ether;
DOI:10.1016/S0040-4039(01)93875-4