13-benzyloxy-13-oxotridecanoic acid

Base Information

• Chemical Name: 13-benzyloxy-13-oxotridecanoic acid
• CAS No.: 261178-55-6
• Molecular Formula: C₂₀H₃₀O₄
• Molecular Weight: 334.456
• Mol file: 261178-55-6.mol

Synonyms:13-benzyloxy-13-oxotridecanoic acid

Chemical Property of 13-benzyloxy-13-oxotridecanoic acid

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 13-benzyloxy-13-oxotridecanoic acid

There total 3 articles about 13-benzyloxy-13-oxotridecanoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

brassylic acid (505-52-2) + benzyl bromide (100-39-0) → 13-benzyloxy-13-oxotridecanoic acid (261178-55-6)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; hexane; water; ethyl acetate; at 0 - 20 ℃;

DOI:10.1016/j.bmc.2016.06.007

Reference yield: 22.0%

brassylic acid (505-52-2) + benzyl bromide (100-39-0) → Dibenzyl-brassylat (52175-11-8) + 13-benzyloxy-13-oxotridecanoic acid (261178-55-6)

Guidance literature:

With potassium hydroxide; tetrabutylammomium bromide; In tetrahydrofuran; methanol; for 6h; Thermolysis;

DOI:10.1021/jo991338i

Reference yield:

tridecanedioic acid + benzyl bromide (100-39-0) → 13-benzyloxy-13-oxotridecanoic acid (261178-55-6)

Guidance literature:

tridecanedioic acid; With potassium hydroxide; In methanol; for 0.333333h;

benzyl bromide; With tetra(n-tert-butyl)ammonium bromide; In toluene; for 6h; Reflux;

upstream raw materials:

brassylic acid

benzyl bromide

Downstream raw materials:

benzyl 11-dodecenoate