(R)-15-Methyl-3-(13-methyl-tetradecanoyloxy)-hexadecanoic acid benzhydryl ester

Base Information

• Chemical Name: (R)-15-Methyl-3-(13-methyl-tetradecanoyloxy)-hexadecanoic acid benzhydryl ester
• CAS No.: 179869-82-0
• Molecular Formula: C₄₅H₇₂O₄
• Molecular Weight: 677.064
• Mol file: 179869-82-0.mol

Synonyms:(R)-15-Methyl-3-(13-methyl-tetradecanoyloxy)-hexadecanoic acid benzhydryl ester

Chemical Property of (R)-15-Methyl-3-(13-methyl-tetradecanoyloxy)-hexadecanoic acid benzhydryl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R)-15-Methyl-3-(13-methyl-tetradecanoyloxy)-hexadecanoic acid benzhydryl ester

There total 4 articles about (R)-15-Methyl-3-(13-methyl-tetradecanoyloxy)-hexadecanoic acid benzhydryl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

13-methyltetradecanoic acid (2485-71-4) + (R)-3-Hydroxy-15-methyl-hexadecanoic acid benzhydryl ester (179869-81-9) → (R)-15-Methyl-3-(13-methyl-tetradecanoyloxy)-hexadecanoic acid benzhydryl ester (179869-82-0)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; for 16h; Ambient temperature;

DOI:10.1016/S0040-4020(98)83044-5

Reference yield:

diazodiphenylmethane (908093-98-1) → (R)-15-Methyl-3-(13-methyl-tetradecanoyloxy)-hexadecanoic acid benzhydryl ester (179869-82-0)

Guidance literature:

Multi-step reaction with 2 steps

1: ethyl acetate / 0.75 h / 50 °C

2: 89 percent / DCC, DMAP / CH₂Cl₂ / 16 h / Ambient temperature

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; ethyl acetate;

DOI:10.1016/S0040-4020(98)83044-5

Reference yield:

(3R)-ethyl-3-hydroxy-15-methylhexadecanoate (75352-11-3) → (R)-15-Methyl-3-(13-methyl-tetradecanoyloxy)-hexadecanoic acid benzhydryl ester (179869-82-0)

Guidance literature:

Multi-step reaction with 2 steps

1: ethyl acetate / 0.75 h / 50 °C

2: 89 percent / DCC, DMAP / CH₂Cl₂ / 16 h / Ambient temperature

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; ethyl acetate;

DOI:10.1016/S0040-4020(98)83044-5

upstream raw materials:

13-methyltetradecanoic acid

(R)-3-Hydroxy-15-methyl-hexadecanoic acid benzhydryl ester

diazodiphenylmethane

(3R)-ethyl-3-hydroxy-15-methylhexadecanoate

Downstream raw materials:

N-[(3R)-15-methyl-3-(13-methyltetradecanoyloxy)hexadecanoyl]glycine benzyl ester

N-{N-[(3R)-15-methyl-3-(13-methyltetradecanoyloxy)hexadecanoyl]glycyl}-D serine

N-{N-[(3R)-15-methyl-3-(13-methyltetradecanoyloxy)hexadecanoyl]-L-seryl}glycine benzyl ester

N-{N-[(3R)-15-methyl-3-(13-methyltetradecanoyloxy)hexadecanoyl]-D-seryl}glycine benzyl ester