(2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropanal

Base Information

Chemical Name:(2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropanal
CAS No.:845536-62-1
Molecular Formula:C₃₇H₆₀O₈Si
Molecular Weight:660.964
Hs Code.:

Synonyms:(2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropanal

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Chemical Property of (2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropanal

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Technology Process of (2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropanal

There total 4 articles about (2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 845536-46-1
(2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropan-1-ol

: 845536-62-1
(2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropanal

Guidance literature:: With tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide; In dichloromethane; at 20 ℃; for 0.666667h;
DOI:10.1021/ol047779s

Reference yield:

: 2'-[benzyl-(2,4,6-trimethylbenzenesulfonyl)amino]-1'-phenylpropyl (2S,3RS,1'S,2'R,2''S,3''S,5''S)-3-[2-(6''-benzyloxy-2''-methoxymethoxy-3'',5''-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-3-hydroxy-2-methylpropionate

: 845536-62-1
(2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropanal

Guidance literature:: Multi-step reaction with 3 steps

1: 89 percent / diisopropylethylamine / CH₂Cl₂ / 0.5 h / 0 °C

2: 89 percent / DIBALH / toluene / 1 h / -78 °C

3: tetrapropylammonium peruthenate; 4-methylmorpholine-N-oxide / CH₂Cl₂ / 0.67 h / 20 °C

With tetrapropylammonium perruthennate; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; N-ethyl-N,N-diisopropylamine; In dichloromethane; toluene;
DOI:10.1021/ol047779s

Reference yield:

: 845536-61-0
2'-[benzyl-(2,4,6-trimethylbenzenesulfonyl)amino]-1'-phenylpropyl (2S,3R,1'S,2'R,2''S,3''S,5''S)-3-[2-(6''-benzyloxy-2''-methoxymethoxy-3'',5''-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxy-propionate

: 845536-62-1
(2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropanal

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / DIBALH / toluene / 1 h / -78 °C

2: tetrapropylammonium peruthenate; 4-methylmorpholine-N-oxide / CH₂Cl₂ / 0.67 h / 20 °C

With tetrapropylammonium perruthennate; diisobutylaluminium hydride; 4-methylmorpholine N-oxide; In dichloromethane; toluene;
DOI:10.1021/ol047779s