Acetic acid (1R,4S,5R,8R)-4-benzenesulfinylmethyl-8-methyl-4-phenyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl ester

Base Information

Chemical Name:Acetic acid (1R,4S,5R,8R)-4-benzenesulfinylmethyl-8-methyl-4-phenyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl ester
CAS No.:779358-33-7
Molecular Formula:C₂₃H₂₆O₅S
Molecular Weight:414.522
Hs Code.:

Synonyms:Acetic acid (1R,4S,5R,8R)-4-benzenesulfinylmethyl-8-methyl-4-phenyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl ester

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Chemical Property of Acetic acid (1R,4S,5R,8R)-4-benzenesulfinylmethyl-8-methyl-4-phenyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl ester

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Technology Process of Acetic acid (1R,4S,5R,8R)-4-benzenesulfinylmethyl-8-methyl-4-phenyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl ester

There total 7 articles about Acetic acid (1R,4S,5R,8R)-4-benzenesulfinylmethyl-8-methyl-4-phenyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 779358-32-6
Acetic acid (1R,4S,5R,8R)-8-methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl ester

: 779358-33-7
Acetic acid (1R,4S,5R,8R)-4-benzenesulfinylmethyl-8-methyl-4-phenyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl ester

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃;
DOI:10.1002/anie.200453859

Reference yield:

: 6090-09-1,57072-59-0,70286-20-3,54973-16-9
methyl-[(1R)-4-methylcyclohex-3-enyl]ketone

: 779358-33-7
Acetic acid (1R,4S,5R,8R)-4-benzenesulfinylmethyl-8-methyl-4-phenyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 64 percent / KHMDS / tetrahydrofuran / -78 - -40 °C

2: 75 percent / Ni(acac)2 / diethyl ether / 20 °C

3: O₂; azobis(isobutyronitrile) / acetonitrile / 0.5 h / 0 °C / Irradiation

4: Ph₃P / acetonitrile; CH₂Cl₂ / 0 - 20 °C

5: 95 percent / 2,6-lutidine / CH₂Cl₂

6: 85 percent / m-chloroperoxybenzoic acid / CH₂Cl₂ / 0 °C

With 2,6-dimethylpyridine; bis(acetylacetonate)nickel(II); 2,2'-azobis(isobutyronitrile); oxygen; potassium hexamethylsilazane; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1002/anie.200453859

Reference yield:

: 4680-24-4
cis-(R)-limonene oxide

: 779358-33-7
Acetic acid (1R,4S,5R,8R)-4-benzenesulfinylmethyl-8-methyl-4-phenyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl ester

Guidance literature:: Multi-step reaction with 8 steps

1.1: O₃ / CH₂Cl₂ / -78 °C

1.2: 50 percent / Zn; acetic acid; sodium iodide / sodium acetate

2.1: 64 percent / KHMDS / tetrahydrofuran / -78 - -40 °C

3.1: 75 percent / Ni(acac)2 / diethyl ether / 20 °C

4.1: O₂; azobis(isobutyronitrile) / acetonitrile / 0.5 h / 0 °C / Irradiation

5.1: Ph₃P / acetonitrile; CH₂Cl₂ / 0 - 20 °C

6.1: 95 percent / 2,6-lutidine / CH₂Cl₂

7.1: 85 percent / m-chloroperoxybenzoic acid / CH₂Cl₂ / 0 °C

With 2,6-dimethylpyridine; bis(acetylacetonate)nickel(II); 2,2'-azobis(isobutyronitrile); oxygen; potassium hexamethylsilazane; ozone; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1002/anie.200453859