Technology Process of 2,6-diisopropylphenyl tert-butyldimethylsilyl ether
There total 3 articles about 2,6-diisopropylphenyl tert-butyldimethylsilyl ether which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
tert-butyldimethylsilanol;
With
sodium hexamethyldisilazane;
In
toluene; pentane;
at 0 - 25 ℃;
for 0.166667h;
Inert atmosphere;
Schlenk technique;
2,6-diisopropylphenyl(2,4,6-trimethoxyphenyl)iodonium tosylate;
In
toluene; pentane;
at 0 - 25 ℃;
for 12h;
Schlenk technique;
Inert atmosphere;
DOI:10.1021/acs.orglett.8b00287
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: sodium perborate tetrahydrate / 17 h / 20 - 40 °C
2.1: dichloromethane / 20 °C
3.1: sodium hexamethyldisilazane / pentane; toluene / 0.17 h / 0 - 25 °C / Inert atmosphere; Schlenk technique
3.2: 12 h / 0 - 25 °C / Schlenk technique; Inert atmosphere
With
sodium perborate tetrahydrate; sodium hexamethyldisilazane;
In
dichloromethane; toluene; pentane;
DOI:10.1021/acs.orglett.8b00287
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: dichloromethane / 20 °C
2.1: sodium hexamethyldisilazane / pentane; toluene / 0.17 h / 0 - 25 °C / Inert atmosphere; Schlenk technique
2.2: 12 h / 0 - 25 °C / Schlenk technique; Inert atmosphere
With
sodium hexamethyldisilazane;
In
dichloromethane; toluene; pentane;
DOI:10.1021/acs.orglett.8b00287
