18173-64-3Relevant articles and documents
Surface oxygen-assisted Pd nanoparticle catalysis for selective oxidation of silanes to silanols
Shimizu, Ken-Ichi,Kubo, Takahiro,Satsuma, Atsushi
, p. 2226 - 2229 (2012)
Just add O2: Based on the fact that an oxygen-adsorbed Pd metal surface shows higher reactivity for water dissociation than a clean Pd surface, carbon-supported Pd nanoparticles (NPs) with surface oxygen atoms were developed as a highly effective and reusable heterogeneous catalyst for selective oxidation of silanes to silanols with water as a green oxidant (see figure). Copyright
Sommer,Evans
, p. 1186 (1954)
Catalysis by cationic oxorhenium(v): Hydrolysis and alcoholysis of organic silanes
Corbin, Rex A.,Ison, Elon A.,Abu-Omar, Mahdi M.
, p. 2850 - 2855 (2009)
The cationic [2-(2′-hydroxyphenyl)-2-oxazolinato(-2)]oxorhenium(v) complex 1 promotes oxidative dehydrogenation of organosilanes with water and alcohols in a catalytic manner to give excellent yields of silanols and silyl ethers, respectively. The reactions proceed conveniently under ambient and open-flask conditions with low catalyst loading (≤1 mol%). The scope of the reaction with water is quite broad and includes aliphatic, aromatic, tertiary, secondary and primary silanes. The rate of reaction depends on the catalyst and silane concentrations and kinetic isotope effect measurements demonstrate involvement of the Si-H bond in the activated complex. The most influential factor on the silane affecting reactivity is steric hindrance and a quantitative correlation with the Taft steric parameter (E) is presented. A combination of kinetic data and isotope labelling results are used to discuss plausible mechanisms for the oxidative dehydrogenation reaction pathway.
Gold nanoparticles supported on the periodic mesoporous organosilica SBA-15 as an efficient and reusable catalyst for selective oxidation of silanes to silanols
Ma, Lina,Leng, Wenguang,Zhao, Yaopeng,Gao, Yanan,Duan, Hongdong
, p. 6807 - 6810 (2014)
Gold nanoparticles are confined and stabilized within the channels of SBA-15 through the poly(ionic liquid) brushes that are anchored onto the pore walls of SBA-15. The supported gold catalyst exhibited remarkably high catalytic activities for selective oxidation of silanes into silanols using water as an oxidant without the use of organic solvents.
Lewis acid-promoted reactions of γ-lactols with silyl enol ethers - Stereoselective formation of functionalized tetrahydrofuran derivatives
Schmitt, Andreas,Reissig, Hans-Ulrich
, p. 1169 - 1174 (2001)
The monosubstituted γ-lactols 1a, 1b, 1c, and 1d and the disubstituted γ-lactol 1e were converted into tetrahydrofuran derivatives by reaction with typical silyl enol ethers in the presence of Lewis acids. Although the most suitable Lewis acid appears to be zinc chloride, BF3·Et2O or diethylaluminium chloride are also suitable under appropriate conditions. The stereoselectivities of these substitution reactions are similar to those observed with other silylated nucleophiles; however, there are several important differences. A comparison of the diastereoselectivities of different γ-lactols and of various silylated nucleophiles and organometallic compounds will also be presented in this paper.
Highly Selective Hydroxylation and Alkoxylation of Silanes: One-Pot Silane Oxidation and Reduction of Aldehydes/Ketones
Luo, Nianhua,Liao, Jianhua,Ouyang, Lu,Wen, Huiling,Zhong, Yuhong,Liu, Jitian,Tang, Weiping,Luo, Renshi
, p. 165 - 171 (2020/01/21)
An efficient chemoselective iridium-catalyzed method for the hydroxylation and alkoxylation of organosilanes to generate hydrogen gas and silanols or silyl ethers was developed. A variety of sterically hindered silanes with alkyl, aryl, and ether groups were tolerated. Furthermore, this atom-economical catalytic protocol can be used for the synthesis of silanediols and silanetriols. A one-pot silane oxidation and chemoselective reduction of aldehydes/ketones was also realized.
Selective Manganese-Catalyzed Oxidation of Hydrosilanes to Silanols under Neutral Reaction Conditions
Wang, Kaikai,Zhou, Jimei,Jiang, Yuting,Zhang, Miaomiao,Wang, Chao,Xue, Dong,Tang, Weijun,Sun, Huamin,Xiao, Jianliang,Li, Chaoqun
supporting information, p. 6380 - 6384 (2019/05/06)
The first manganese-catalyzed oxidation of organosilanes to silanols with H2O2 under neutral reaction conditions has been accomplished. A variety of organosilanes with alkyl, aryl, alknyl, and heterocyclic substituents were tolerated, as well as sterically hindered organosilanes. The oxidation appears to proceed by a concerted process involving a manganese hydroperoxide species. Featuring mild reaction conditions, fast oxidation, and no waste byproducts, the protocol allows a low-cost, eco-benign synthesis of both silanols and silanediols.