trans carveol 3,5-dinitrobenzoate

Base Information

• Chemical Name: trans carveol 3,5-dinitrobenzoate
• CAS No.: 57457-95-1
• Molecular Formula: C₁₇H₁₈N₂O₆
• Molecular Weight: 346.34
• Mol file: 57457-95-1.mol

Synonyms:trans carveol 3,5-dinitrobenzoate

Chemical Property of trans carveol 3,5-dinitrobenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans carveol 3,5-dinitrobenzoate

There total 18 articles about trans carveol 3,5-dinitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

Imidazole-1-carbothioic acid O-((1S,4R,6S)-4-isopropenyl-1-methyl-7-oxa-bicyclo[4.1.0]hept-2-yl) ester (79307-11-2,79356-24-4,79356-25-5) + 3,5-dinitrobenoyl chloride (99-33-2) → (+)-cis-carveol 3,5-dinitrobenzoate (57429-67-1,57457-95-1,98392-82-6)

Guidance literature:

With pyridine; naphthalene; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; Heating;

DOI:10.1039/P19810002363

Reference yield:

Pinene (80-56-8,177698-18-9,25766-18-1) → (+/-)-trans-carveol 3,5-dinitrobenzoate (57429-67-1,57457-95-1,98392-82-6)

Guidance literature:

Multi-step reaction with 3 steps

1: I₂ / benzene / 1 h / Heating

2: 8.5 g / 10percent ethanolic KOH

3: pyridine / 120 h / Ambient temperature

With pyridine; potassium hydroxide; iodine; In benzene;

Reference yield:

trans-(S)-(-)-limoneneoxide (42477-94-1) → (+)-cis-carveol 3,5-dinitrobenzoate (57429-67-1,57457-95-1,98392-82-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 86 percent / CH₂Cl₂ / Heating

2: 47 percent / tri-n-butyltin hydride, azobisisobutyronitrile, pyridine, naphtalene / benzene / Heating

With pyridine; naphthalene; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In dichloromethane; benzene;

DOI:10.1039/P19810002363

upstream raw materials:

(4R,6R)-carveol

(-)-trans-carveol

3,5-dinitrobenoyl chloride

(R)-Carvone

Downstream raw materials:

(+/-)-trans-carveol 3,5-dinitrobenzoate

(+/-)-O-(3.5-dinitro-benzoyl)-cis-carveol

cis-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-ol

(+/-)-trans-carveol