3,5-dinitrobenzoate ester of (+)-trans-carveol

Base Information

• Chemical Name: 3,5-dinitrobenzoate ester of (+)-trans-carveol
• CAS No.: 57429-67-1
• Molecular Formula: C₁₇H₁₈N₂O₆
• Molecular Weight: 346.34
• Mol file: 57429-67-1.mol

Synonyms:3,5-dinitrobenzoate ester of (+)-trans-carveol

Chemical Property of 3,5-dinitrobenzoate ester of (+)-trans-carveol

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 3,5-dinitrobenzoate ester of (+)-trans-carveol

There total 20 articles about 3,5-dinitrobenzoate ester of (+)-trans-carveol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

Imidazole-1-carbothioic acid O-((1R,4R,6R)-4-isopropenyl-1-methyl-7-oxa-bicyclo[4.1.0]hept-2-yl) ester (79307-11-2,79356-24-4,79356-25-5) + 3,5-dinitrobenoyl chloride (99-33-2) → 3,5-dinitrobenzoate ester of (+)-trans-carveol (57429-67-1)

Guidance literature:

With pyridine; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; Heating;

DOI:10.1039/P19810002363

Reference yield: 47.0%

Imidazole-1-carbothioic acid O-((1S,4R,6S)-4-isopropenyl-1-methyl-7-oxa-bicyclo[4.1.0]hept-2-yl) ester (79307-11-2,79356-24-4,79356-25-5) + 3,5-dinitrobenoyl chloride (99-33-2) → (+)-cis-carveol 3,5-dinitrobenzoate (57429-67-1,57457-95-1,98392-82-6)

Guidance literature:

With pyridine; naphthalene; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; Heating;

DOI:10.1039/P19810002363

Reference yield:

Pinene (80-56-8,177698-18-9,25766-18-1) → (+/-)-trans-carveol 3,5-dinitrobenzoate (57429-67-1,57457-95-1,98392-82-6)

Guidance literature:

Multi-step reaction with 3 steps

1: I₂ / benzene / 1 h / Heating

2: 8.5 g / 10percent ethanolic KOH

3: pyridine / 120 h / Ambient temperature

With pyridine; potassium hydroxide; iodine; In benzene;

upstream raw materials:

(2S,4S)-carveol

(+)-trans-carveol

3,5-dinitrobenoyl chloride

Imidazole-1-carbothioic acid O-((1R,4R,6R)-4-isopropenyl-1-methyl-7-oxa-bicyclo[4.1.0]hept-2-yl) ester

Downstream raw materials:

(+/-)-trans-carveol 3,5-dinitrobenzoate

(+/-)-O-(3.5-dinitro-benzoyl)-cis-carveol

(2S,4S)-carveol

cis-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-ol