C₆₁H₉₁NO₈Si

Base Information

• Chemical Name: C₆₁H₉₁NO₈Si
• CAS No.: 1372783-06-6
• Molecular Formula: C₆₁H₉₁NO₈Si
• Molecular Weight: 994.481
• Mol file: 1372783-06-6.mol

Synonyms:C₆₁H₉₁NO₈Si

Chemical Property of C₆₁H₉₁NO₈Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₁H₉₁NO₈Si

There total 3 articles about C₆₁H₉₁NO₈Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

4-(2,5-didodecyloxy-4-iodophenylethynyl)-pyridine-2,6-dicarboxylic acid dimethyl ester (861108-92-1) + ethynyl-4-[[6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]hexyl]oxy]-benzene (1372783-05-5) → C61H91NO8Si (1372783-06-6)

Guidance literature:

4-(2,5-didodecyloxy-4-iodophenylethynyl)-pyridine-2,6-dicarboxylic acid dimethyl ester; With copper(l) iodide; diisopropylamine; In tetrahydrofuran; at 20 ℃; for 0.25h; Inert atmosphere; Darkness;

ethynyl-4-[[6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]hexyl]oxy]-benzene; In tetrahydrofuran; at 20 ℃; for 6h;

DOI:10.1002/anie.201107655

Reference yield:

tert-butyldimethylsilyl chloride (18162-48-6) → C61H91NO8Si (1372783-06-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 3 h / 20 °C

2.1: copper(l) iodide; diisopropylamine / tetrahydrofuran / 0.25 h / 20 °C / Inert atmosphere; Darkness

2.2: 6 h / 20 °C

With 1H-imidazole; copper(l) iodide; diisopropylamine; In tetrahydrofuran; N,N-dimethyl-formamide;

DOI:10.1002/anie.201107655

Reference yield:

4-Ethynyl-1-(6-hydroxyhexane-1-yloxy)benzene (154962-37-5) → C61H91NO8Si (1372783-06-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 1H-imidazole / N,N-dimethyl-formamide / 3 h / 20 °C

2.1: copper(l) iodide; diisopropylamine / tetrahydrofuran / 0.25 h / 20 °C / Inert atmosphere; Darkness

2.2: 6 h / 20 °C

With 1H-imidazole; copper(l) iodide; diisopropylamine; In tetrahydrofuran; N,N-dimethyl-formamide;

DOI:10.1002/anie.201107655

upstream raw materials:

4-(2,5-didodecyloxy-4-iodophenylethynyl)-pyridine-2,6-dicarboxylic acid dimethyl ester

ethynyl-4-[[6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]hexyl]oxy]-benzene

tert-butyldimethylsilyl chloride

4-Ethynyl-1-(6-hydroxyhexane-1-yloxy)benzene

Downstream raw materials:

C₅₉H₈₇NO₈Si