10-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthen-4-yl)-5,15-bis(pentafluorophenyl)cobaltcorrole

Base Information

Chemical Name:10-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthen-4-yl)-5,15-bis(pentafluorophenyl)cobaltcorrole
CAS No.:1260854-59-8
Molecular Formula:C₅₅H₃₇CoF₁₀N₄O₃
Molecular Weight:1050.9
Hs Code.:

Synonyms:10-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthen-4-yl)-5,15-bis(pentafluorophenyl)cobaltcorrole

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Chemical Property of 10-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthen-4-yl)-5,15-bis(pentafluorophenyl)cobaltcorrole

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Technology Process of 10-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthen-4-yl)-5,15-bis(pentafluorophenyl)cobaltcorrole

There total 7 articles about 10-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthen-4-yl)-5,15-bis(pentafluorophenyl)cobaltcorrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 10-(4-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthenyl))-5,15-bis(pentafluorophenyl)corrole

: 1260854-59-8
10-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthen-4-yl)-5,15-bis(pentafluorophenyl)cobaltcorrole

Guidance literature:: With cobalt(II) acetate; In acetonitrile; at 85 - 95 ℃; for 0.333333h; Microwave irradiation;
DOI:10.1021/ja108904s

Reference yield:

: 405175-86-2
5-bromo-2,7-di-tert-butyl-9,9-dimethylxanthene-4-carbaldehyde

: 1260854-59-8
10-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthen-4-yl)-5,15-bis(pentafluorophenyl)cobaltcorrole

Guidance literature:: Multi-step reaction with 6 steps

1.1: toluene-4-sulfonic acid / toluene / Inert atmosphere; Reflux

2.1: phenyllithium / tetrahydrofuran; hexane

3.1: sulfuric acid / Reflux

4.1: trifluoroacetic acid / dichloromethane / 7 h / 20 °C

4.2: 0.25 h / 20 °C

5.1: sodium hydroxide / tetrahydrofuran; water / 6 h / 75 - 85 °C / Microwave irradiation

5.2: 20 °C

6.1: cobalt(II) acetate / acetonitrile / 0.33 h / 85 - 95 °C / Microwave irradiation

With sulfuric acid; cobalt(II) acetate; toluene-4-sulfonic acid; phenyllithium; trifluoroacetic acid; sodium hydroxide; In tetrahydrofuran; hexane; dichloromethane; water; toluene; acetonitrile;
DOI:10.1021/ja108904s

Reference yield:

: 405175-89-5
2,7-di-tert-butyl-5-formyl-9,9-dimethyl-xanthene-4-carboxylic acid

: 1260854-59-8
10-(5-hydroxycarbonyl-2,7-di-tert-butyl-9,9-dimethylxanthen-4-yl)-5,15-bis(pentafluorophenyl)cobaltcorrole

Guidance literature:: Multi-step reaction with 4 steps

1.1: sulfuric acid / Reflux

2.1: trifluoroacetic acid / dichloromethane / 7 h / 20 °C

2.2: 0.25 h / 20 °C

3.1: sodium hydroxide / tetrahydrofuran; water / 6 h / 75 - 85 °C / Microwave irradiation

3.2: 20 °C

4.1: cobalt(II) acetate / acetonitrile / 0.33 h / 85 - 95 °C / Microwave irradiation

With sulfuric acid; cobalt(II) acetate; trifluoroacetic acid; sodium hydroxide; In tetrahydrofuran; dichloromethane; water; acetonitrile;
DOI:10.1021/ja108904s