(N(2-PPh₂-4-Me-C₆H₃)2)Ir(COE)

Base Information

• Chemical Name: (N(2-PPh₂-4-Me-C₆H₃)2)Ir(COE)
• CAS No.: 1255934-46-3
• Molecular Formula: C₄₆H₄₆IrNP₂
• Molecular Weight: 867.045
• Mol file: 1255934-46-3.mol

Synonyms:(N(2-PPh₂-4-Me-C₆H₃)2)Ir(COE)

Chemical Property of (N(2-PPh₂-4-Me-C₆H₃)2)Ir(COE)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (N(2-PPh₂-4-Me-C₆H₃)2)Ir(COE)

There total 2 articles about (N(2-PPh₂-4-Me-C₆H₃)2)Ir(COE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

chlorobis(cyclooctene)-iridium(I) dimer + bis(2-(diphenylphosphaneyl)-4-methylphenyl)amine (1011473-19-0) → (N(2-PPh2-4-Me-C6H3)2)Ir(COE) (1255934-46-3)

Guidance literature:

With LiN(Si(CH₃)3)2; In fluorobenzene; byproducts: LiCl; (N2); a flask loaded with ligand, Li compd. and C6H5F, stirred for 1 h at ambient temp., added to a suspn. of Ir complex, stirred for 1 h; filtered, washed (CH2Cl2), concd., washed (hexanes), filtered, dried (vac.); elem. anal.;

DOI:10.1039/b925856f

Reference yield: 33.0%

chlorobis(cyclooctene)-iridium(I) dimer + bis(2-(diphenylphosphaneyl)-4-methylphenyl)amine (1011473-19-0) → (HN(2-PPh2-4-Me-C6H3)2)IrHCl2 (1255934-44-1) + (N(2-PPh2-4-Me-C6H3)2)Ir(COE) (1255934-46-3)

Guidance literature:

In benzene; (N2); a soln. of ligand added to a suspn. of Ir complex, stirred at ambient temp. for 18 h; filtered, washed (C6H6), dried (vac.); elem. anal.;

DOI:10.1039/b925856f

Reference yield: 83.0%

triethylsilane (617-86-7) + (N(2-PPh2-4-Me-C6H3)2)Ir(COE) (1255934-46-3) → (N(2-PPh2-4-Me-C6H3)2)IrH(SiEt3) (1255934-65-6)

Guidance literature:

In toluene; byproducts: C8H14; (N2); a soln. of HSi(C2H5)3 added to a soln. of Ir complex, heated in a sealed vessel at 80-85°C for 4.5 h; evapd. (vac.), crystd. by diffusion of pentane into a CH2Cl2 soln.; elem. anal.;

DOI:10.1039/b925856f

upstream raw materials:

bis(2-(diphenylphosphaneyl)-4-methylphenyl)amine

Downstream raw materials:

(N(2-PPh₂-4-Me-C₆H₃)2)IrMe(I)(THF)

(N(2-PPh₂-4-Me-C₆H₃)2)IrH(SiEt₃)

(N(2-PPh₂-4-Me-C₆H₃)2)IrH(SiPh₃)