Diiodotriphenylphosphorane

Base Information

Chemical Name:Diiodotriphenylphosphorane
CAS No.:6396-07-2
Molecular Formula:C18H15 I2 P
Molecular Weight:516.1
Hs Code.:
European Community (EC) Number:627-787-9
DSSTox Substance ID:DTXSID70213802
Nikkaji Number:J50.355J
Wikidata:Q83089404
Mol file:6396-07-2.mol

Synonyms:Diiodotriphenylphosphorane;6396-07-2;Phosphorane, diiodotriphenyl-;Iodotriphenylphosphoranium iodide;diiodo(triphenyl)-lambda5-phosphane;BRN 2740417;I2-PPh3;diiodo(triphenyl)-5-phosphane;SCHEMBL525224;DIIDOTRIPHENYLPHOSPHORANE;DTXSID70213802;AC9088;MFCD00216568;AKOS015916033;SY263442;LS-107452;CS-0203211;4-16-00-01013 (Beilstein Handbook Reference);Triphenylphosphine diiodide, technical grade, 90%

Suppliers and Price of Diiodotriphenylphosphorane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
TRIPHENYLPHOSPHINE DIIODIDE 95.00%
5G
$ 528.00

American Custom Chemicals Corporation
TRIPHENYLPHOSPHINE DIIODIDE 95.00%
1G
$ 425.60

American Custom Chemicals Corporation
TRIPHENYLPHOSPHINE DIIODIDE 95.00%
100ML
$ 2387.50

AK Scientific
Diiodotriphenylphosphorane
5g
$ 802.00

Total 14 raw suppliers

Chemical Property of Diiodotriphenylphosphorane

Chemical Property:

Melting Point:210-220 °C(lit.)
PSA：13.59000
LogP:5.21620
Storage Temp.:2-8°C
Sensitive.:Light Sensitive
XLogP3:6.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:515.90008
Heavy Atom Count:21
Complexity:285

Purity/Quality:

98%,99%, ^*data from raw suppliers

TRIPHENYLPHOSPHINE DIIODIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:C
Statements: 34-42/43-62
Safety Statements: 26-36/37/39-45

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(C2=CC=CC=C2)(C3=CC=CC=C3)(I)I
Uses Triphenylphosphine diiodide (Ph3P. I2) can be used as a reagent: To facilitate the conversion of alcohol, thiol, and enol functional groups into alkyl iodides via formation of alkoxyphosphonium iodide. To prepare β-iodo-α,β-unsaturated ketones from cyclic β-diketones in the presence of triethyl amine. In the synthesis of alkyl nitrates from alcohols. In the Beckmann rearrangement reaction to synthesize lactams from cycloalkanone oxime. For the preparation of aromatic and aliphatic carboxylic acid esters in the presence of N,N-dimethylaminopyridine. Ph3P. I2 can also be used to reduce graphene oxide for the production of graphene nanosheets under mild and environmentally friendly conditions.

Technology Process of Diiodotriphenylphosphorane

There total 8 articles about Diiodotriphenylphosphorane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%