[(η⁵-C₅Me₄CH₂Ph)Ti(III)(η⁵:η¹-C₅Me₄CH₂-o-C₆H₄)]

Base Information

Chemical Name:[(η⁵-C₅Me₄CH₂Ph)Ti(III)(η⁵:η¹-C₅Me₄CH₂-o-C₆H₄)]
CAS No.:1169516-82-8
Molecular Formula:C₃₂H₃₇Ti
Molecular Weight:469.526
Hs Code.:

[(η<sup>5</sup>-C<sub>5</sub>Me<sub>4</sub>CH<sub>2</sub>Ph)Ti(III)(η<sup>5</sup>:η<sup>1</sup>-C<sub>5</sub>Me<sub>4</sub>CH<sub>2</sub>-o-C<sub>6</sub>H<sub>4</sub>)]

Synonyms:[(η⁵-C₅Me₄CH₂Ph)Ti(III)(η⁵:η¹-C₅Me₄CH₂-o-C₆H₄)]

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Chemical Property of [(η⁵-C₅Me₄CH₂Ph)Ti(III)(η⁵:η¹-C₅Me₄CH₂-o-C₆H₄)]

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Technology Process of [(η⁵-C₅Me₄CH₂Ph)Ti(III)(η⁵:η¹-C₅Me₄CH₂-o-C₆H₄)]

There total 1 articles about [(η⁵-C₅Me₄CH₂Ph)Ti(III)(η⁵:η¹-C₅Me₄CH₂-o-C₆H₄)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1169516-79-3
[TiCl(η5-C5Me4(CH2Ph))2]

: 1169516-82-8
[(η⁵-C₅Me₄CH₂Ph)Ti(III)(η⁵:η¹-C₅Me₄CH₂-o-C₆H₄)]

Guidance literature:: With CH₃Li; In hexane; byproducts: LiCl, CH4; soln. of Ti compd. in hexane poured onto solid MeLi, mixt. shaken at 60°C for ca. 4 h; solid sepd. and repeatedly extd. with hexane, combined extracts concd., cooled at -28°C overnight, soln. decanted from white ppt., concd., crystn. on cooling at -28°C, crystals dried under vac.; elem. anal.;
DOI:10.1016/j.jorganchem.2009.01.039

Reference yield: 91.0%

: 1169516-82-8
[(η⁵-C₅Me₄CH₂Ph)Ti(III)(η⁵:η¹-C₅Me₄CH₂-o-C₆H₄)]

: 7758-95-4
lead(II) chloride

: 1169516-83-9
[TiCl(η5-C5Me4(CH2Ph))(η5:η1-C5Me4CH2-o-C6H4)]

Guidance literature:: In tetrahydrofuran; byproducts: Pb; soln. of Ti compd. (0.64 mmol) in THF poured onto PbCl2 powder, mixt. v igorously stirred for 20 min; soln. sepd., evapd., residue dissolved in hexane, concd., solid sepd. and recrystd. from hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2009.01.039