C₆₁H₁₁₃NO₁₃Si₃

Base Information

• Chemical Name: C₆₁H₁₁₃NO₁₃Si₃
• CAS No.: 740834-75-7
• Molecular Formula: C₆₁H₁₁₃NO₁₃Si₃
• Molecular Weight: 1152.82
• Mol file: 740834-75-7.mol

Synonyms:C₆₁H₁₁₃NO₁₃Si₃

Chemical Property of C₆₁H₁₁₃NO₁₃Si₃

Chemical Property:

Purity/Quality:

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Technology Process of C₆₁H₁₁₃NO₁₃Si₃

There total 2 articles about C₆₁H₁₁₃NO₁₃Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

C62H115NO13Si3 (740834-74-6) → C61H113NO13Si3 (740834-75-7)

Guidance literature:

With calcium hydroxide; In tetrahydrofuran; water; at 20 ℃; for 40h;

DOI:10.1016/j.tet.2004.05.028

Reference yield:

C61H111NO12Si3 (649748-30-1) → C61H113NO13Si3 (740834-75-7)

Guidance literature:

Multi-step reaction with 2 steps

1.1: Ca(OH)2 / tetrahydrofuran; H₂O / 0.5 h / 20 °C

1.2: 86 percent / CH₂Cl₂; diethyl ether

2.1: 96 percent / Ca(OH)2 / tetrahydrofuran; H₂O / 40 h / 20 °C

With calcium hydroxide; In tetrahydrofuran; water;

DOI:10.1016/j.tet.2004.05.028

Reference yield:

C61H113NO13Si3 (740834-75-7) → (E)-(8S,11S,12R,13S,16R,20S,22S,23R,24S,26R)-16-Ethyl-1,13-dihydroxy-11-[(E)-2-((1R,3R,4R)-4-hydroxy-3-methoxy-cyclohexyl)-1-methyl-vinyl]-22,24-dimethoxy-12,18,20,26-tetramethyl-10,27-dioxa-3-aza-tricyclo[21.3.1.03,8]heptacos-17-ene-2,9,15-trione

Guidance literature:

Multi-step reaction with 3 steps

1: 0.13 h / 160 °C

2: 87 percent / Dess-Martin periodinane / CH₂Cl₂ / 5 h / 20 °C

3: 82 percent / aq. HF / acetonitrile / 20 °C

With hydrogen fluoride; Dess-Martin periodane; In dichloromethane; acetonitrile;

DOI:10.1016/j.tet.2004.05.028

upstream raw materials:

C₆₂H₁₁₅NO₁₃Si₃

C₆₁H₁₁₁NO₁₂Si₃

Downstream raw materials:

C₆₀H₁₁₁NO₁₁Si₃