{Ir(Se₂)(((C₆H₅)2PCH₂)2)2}⁽¹⁺⁾*Cl^(1-)={Ir(Se₂)(((C₆H₅)2PCH₂)2)2}Cl

Base Information

• Chemical Name: {Ir(Se₂)(((C₆H₅)2PCH₂)2)2}⁽¹⁺⁾*Cl^(1-)={Ir(Se₂)(((C₆H₅)2PCH₂)2)2}Cl
• CAS No.: 40603-51-8
• Molecular Formula: C₅₂H₄₈IrP₄Se₂*Cl
• Molecular Weight: 1182.44
• Mol file: 40603-51-8.mol

Synonyms:{Ir(Se₂)(((C₆H₅)2PCH₂)2)2}⁽¹⁺⁾*Cl^(1-)={Ir(Se₂)(((C₆H₅)2PCH₂)2)2}Cl

Chemical Property of {Ir(Se₂)(((C₆H₅)2PCH₂)2)2}⁽¹⁺⁾*Cl^(1-)={Ir(Se₂)(((C₆H₅)2PCH₂)2)2}Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Ir(Se₂)(((C₆H₅)2PCH₂)2)2}⁽¹⁺⁾*Cl^(1-)={Ir(Se₂)(((C₆H₅)2PCH₂)2)2}Cl

There total 4 articles about {Ir(Se₂)(((C₆H₅)2PCH₂)2)2}⁽¹⁺⁾*Cl^(1-)={Ir(Se₂)(((C₆H₅)2PCH₂)2)2}Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

bis(1,2-bis(diphenylphosphino)ethane)iridium(I) chloride (15390-38-2,15131-25-6) + titanocene pentaselenide (12307-22-1) → [Ir(1,2-bis(diphenylphosphino)ethane)2Se2]Cl (40603-51-8)

Guidance literature:

In dichloromethane; at 25°C for 10 min; evapn. of the solvent, washing with THF, recrystn. from CH2Cl2-Et2O;

Reference yield: 90.0%

bis(1,2-bis(diphenylphosphino)ethane)iridium(I) chloride (15390-38-2,15131-25-6) + (MeCp)2TiSe5 (78614-88-7) → [Ir(1,2-bis(diphenylphosphino)ethane)2Se2]Cl (40603-51-8)

Guidance literature:

In dichloromethane; at 25°C for 10 min; evapn. of the solvent, washing with THF, recrystn. from CH2Cl2-Et2O;

Reference yield: 85.0%

bis(1,2-bis(diphenylphosphino)ethane)iridium(I) chloride (15390-38-2,15131-25-6) + selenium (12597-33-0) → {Ir(Se2)(((C6H5)2PCH2)2)2}(1+)*Cl(1-)={Ir(Se2)(((C6H5)2PCH2)2)2}Cl (40603-51-8)

Guidance literature:

In dichloromethane; (N2 or Ar); stirred at room temp. for 8 d; filtered, pptd. (Et2O), filtered, washed with Et2O, dried (room temp.),recrystd. (CH2Cl2/C6H6), dried at 82°C and 1E-3 mmHg; elem. anal.;

DOI:10.1021/ic00140a016

upstream raw materials:

bis(1,2-bis(diphenylphosphino)ethane)iridium(I) chloride

selenium

titanocene pentaselenide

(MeCp)2TiSe₅

Downstream raw materials:

[Ir(Se₂)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2]⁽¹⁺⁾*Cl^(1-)*H₂O*0.5C₆H₆=[Ir(Se₂)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2]Cl*H₂O*0.5C₆H₆

[(((C₆H₅)2PCH₂)2)2IrSe₂IrCl(CO)(P(C₂H₅)2C₆H₅)2]⁽¹⁺⁾*Cl^(1-)=[(((C₆H₅)2PCH₂)2)2IrSe₂IrCl(CO)(P(C₂H₅)2C₆H₅)2]Cl

[(IrSeCl(CO)(P(C₂H₅)2C₆H₅)2)2]

{Ir(S₂)(((C₆H₅)2PCH₂)2)2}⁽¹⁺⁾*Cl^(1-)={Ir(S₂)(((C₆H₅)2PCH₂)2)2}Cl

Refernces

• 1、 Ginsberg,Lindsell,Sprinkle,West,Cohen. "Disulfur and diselenium complexes of rhodium and iridium". . p. 3666 - 3681. Retrieved 2008/10/08.