2,3-diphenylbenzozirconocene

Base Information

• Chemical Name: 2,3-diphenylbenzozirconocene
• CAS No.: 261926-22-1
• Molecular Formula: C₃₀H₂₄Zr
• Molecular Weight: 475.745
• Mol file: 261926-22-1.mol

Synonyms:2,3-diphenylbenzozirconocene

Chemical Property of 2,3-diphenylbenzozirconocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3-diphenylbenzozirconocene

There total 1 articles about 2,3-diphenylbenzozirconocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

C22H22Zr + diphenyl acetylene (501-65-5) → 2,3-diphenylbenzozirconocene (261926-22-1)

Guidance literature:

In toluene; at 110 ℃; for 48h; Schlenk technique; Inert atmosphere; Glovebox;

DOI:10.1002/anie.201809357

Reference yield: 86.0%

2,3-diphenylbenzozirconocene (261926-22-1) + germaniumtetrachloride (10038-98-9) → 1,1-dichloro-2,3-diphenylgermaindene (268207-83-6)

Guidance literature:

In tetrahydrofuran; under Ar; addn. of GeCl4 to soln. of Zr complex in THF, stirring at 50°C for 24 h; evapn. under vac., washing with hexane; elem. anal.;

DOI:10.1021/om990991t

Reference yield: 72.0%

2,3-diphenylbenzozirconocene (261926-22-1) + antimony(III) chloride (10025-91-9) → 1-chloro-2,3-diphenylstibaindole

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 48h; Inert atmosphere; Schlenk technique;

DOI:10.1021/acs.organomet.7b00419

upstream raw materials:

diphenyl acetylene

Downstream raw materials:

1,1-dichloro-2,3-diphenylgermaindene

2,3-diphenyl-1H-indene