(E)-2-(Toluene-4-sulfonyl)-deca-4,9-dienoic acid methyl ester

Base Information

• Chemical Name: (E)-2-(Toluene-4-sulfonyl)-deca-4,9-dienoic acid methyl ester
• CAS No.: 86453-41-0
• Molecular Formula: C₁₈H₂₄O₄S
• Molecular Weight: 336.452
• Mol file: 86453-41-0.mol

Synonyms:(E)-2-(Toluene-4-sulfonyl)-deca-4,9-dienoic acid methyl ester

Chemical Property of (E)-2-(Toluene-4-sulfonyl)-deca-4,9-dienoic acid methyl ester

Chemical Property:

Purity/Quality:

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Technology Process of (E)-2-(Toluene-4-sulfonyl)-deca-4,9-dienoic acid methyl ester

There total 1 articles about (E)-2-(Toluene-4-sulfonyl)-deca-4,9-dienoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

methyl 2-(p-tolylsulfonyl)acetate (50397-64-3) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → (E)-2-(Toluene-4-sulfonyl)-deca-4,9-dienoic acid methyl ester (86453-41-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; sodium phenoxide; In benzene; at 85 ℃; for 16h;

DOI:10.1007/BF00953090

Reference yield: 90.0%

(E)-2-(Toluene-4-sulfonyl)-deca-4,9-dienoic acid methyl ester (86453-41-0) → methyl ester of 2-p-tolylsulfonyl-4-(E)-9-oxodecene-1-carboxylic acid

Guidance literature:

With water; oxygen; copper(l) chloride; palladium dichloride; In N,N-dimethyl-formamide; for 6h;

DOI:10.1007/BF00953090

Reference yield:

(E)-2-(Toluene-4-sulfonyl)-deca-4,9-dienoic acid methyl ester (86453-41-0) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → (E)-2-((E)-Octa-2,7-dienyl)-2-(toluene-4-sulfonyl)-deca-4,9-dienoic acid methyl ester

Guidance literature:

With sodium phenoxide; Pd catalyst;

DOI:10.1007/BF00925314

upstream raw materials:

methyl 2-(p-tolylsulfonyl)acetate

buta-1,3-diene