Technology Process of C21H34O3Si
There total 2 articles about C21H34O3Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C23H36O4Si;
With
diisobutylaluminium hydride;
In
hexane; dichloromethane;
at -78 - -50 ℃;
for 0.5h;
With
methanol; Rochelle's salt;
In
hexane; dichloromethane; water;
at -78 - 20 ℃;
DOI:10.1016/j.tet.2010.11.017
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: ozone / dichloromethane / -78 °C
1.2: -78 - 20 °C
2.1: sodium hydride / tetrahydrofuran; mineral oil / 0.33 h / 0 °C
2.2: 11 h / -78 °C
3.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.67 h / -78 °C
3.2: -78 - 20 °C
4.1: manganese(IV) oxide / 4.5 h / 20 °C
5.1: sodium hydride / tetrahydrofuran; mineral oil / 0.5 h / 0 °C
5.2: 10 h / -78 - 40 °C
6.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.5 h / -78 - -50 °C
6.2: -78 - 20 °C
With
manganese(IV) oxide; sodium hydride; diisobutylaluminium hydride; ozone;
In
tetrahydrofuran; hexane; dichloromethane; mineral oil;
2.1: Horner-Wadsworth-Emmons olefination / 2.2: Horner-Wadsworth-Emmons olefination / 5.1: Horner-Wadsworth-Emmons olefination / 5.2: Horner-Wadsworth-Emmons olefination;
DOI:10.1016/j.tet.2010.11.017
- Guidance literature:
-
With
tetrabutyl ammonium fluoride;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 13h;
DOI:10.1016/j.tet.2010.11.017
