[(1,1,1-tris-(diphenylphosphinomethyl)ethane)Ru(η²-OAc)Cl]

Base Information

• Chemical Name: [(1,1,1-tris-(diphenylphosphinomethyl)ethane)Ru(η²-OAc)Cl]
• CAS No.: 1003045-51-9
• Molecular Formula: C₄₃H₄₂ClO₂P₃Ru
• Molecular Weight: 820.25
• Mol file: 1003045-51-9.mol

Synonyms:[(1,1,1-tris-(diphenylphosphinomethyl)ethane)Ru(η²-OAc)Cl]

Chemical Property of [(1,1,1-tris-(diphenylphosphinomethyl)ethane)Ru(η²-OAc)Cl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(1,1,1-tris-(diphenylphosphinomethyl)ethane)Ru(η²-OAc)Cl]

There total 2 articles about [(1,1,1-tris-(diphenylphosphinomethyl)ethane)Ru(η²-OAc)Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

RuCl(OAc)(PPh3)3 (55978-89-7) + [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] (22031-12-5) → [RuCl(acetate)(κ3-1,1,1-tris(diphenylphosphinomethyl)ethane)] (1003045-51-9)

Guidance literature:

In toluene; byproducts: PPh3; (N2); std. Schlenk technique; suspn. of Ru complex and ligand in toluenewas refluxed for 30 min; cooled to room temp.; filtered; washed (toluene, Et2O); elem. anal.;

DOI:10.1021/ic701773a

Reference yield:

[RuH(OAc-κ2O,O’)(triphos)] (1003045-52-0) + triethylamine hydrochloride (554-68-7) → [RuCl(acetate)(κ3-1,1,1-tris(diphenylphosphinomethyl)ethane)] (1003045-51-9)

Guidance literature:

In dichloromethane-d2; byproducts: H2; (Ar); std. Schlenk technique; Et3N*HCl (3 equiv.) was added to soln. of Ru complex in CD2Cl2; NMR monitoring;

DOI:10.1021/ic701773a

Reference yield: 90.0%

ammonium hexafluorophosphate + [RuCl(acetate)(κ3-1,1,1-tris(diphenylphosphinomethyl)ethane)] (1003045-51-9) + dmpm (64065-08-3) → [RuCl(kappa.2-Me2PCH2PMe2)(κ3-1,1,1-tris(diphenylphosphinomethyl)ethane)]PF6

Guidance literature:

In 1,2-dichloro-ethane; (Ar); std. Schlenk technique; ligand was added to suspn. of Ru complex and NH4PF6 in C2H4Cl2; heated at 50°C for 3 h; filtered; concd.; Et2O added; filtered; washed (Et2O); dried (vac.); elem. anal.;

DOI:10.1021/ic701773a

upstream raw materials:

[RuH(OAc-κ²O,O’)(triphos)]

triethylamine hydrochloride

RuCl(OAc)(PPh₃)3

[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]

Downstream raw materials:

[RuH(OAc-κ²O,O’)(triphos)]