cis-(PPh₃)2Pt(SCH₂Ph)2

Base Information

Chemical Name:cis-(PPh₃)2Pt(SCH₂Ph)2
CAS No.:75365-64-9
Molecular Formula:C₅₀H₄₄P₂PtS₂
Molecular Weight:966.059
Hs Code.:

cis-(PPh<sub>3</sub>)2Pt(SCH<sub>2</sub>Ph)2

Synonyms:cis-(PPh₃)2Pt(SCH₂Ph)2

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Chemical Property of cis-(PPh₃)2Pt(SCH₂Ph)2

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Technology Process of cis-(PPh₃)2Pt(SCH₂Ph)2

There total 1 articles about cis-(PPh₃)2Pt(SCH₂Ph)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 10199-34-5,14056-88-3,15604-36-1
cis-dichlorobis(triphenylphosphine)platinum(II)

: 100-53-8
phenylmethanethiol

: 75365-64-9
cis-(PPh₃)2Pt(SCH₂Ph)2

Guidance literature:: With triethylamine; In toluene; (N2); benzyl mercaptan and (C2H5)3N in toluene added dropwise to stirred complex suspn., stirred at room temp. for 20 h; evapd. (vac., room temp.), dissolved in CH2Cl2, washed with H2O, dried (MgSO4), evapd., recrystd. (CH2Cl2/ether, -12°C), washed with Et2O, dried (N2); elem. anal.;
DOI:10.1021/ic50216a032

Reference yield: 69.0%

: 75365-64-9
cis-(PPh₃)2Pt(SCH₂Ph)2

: μμ'-bis(phenylmethanethiolato)bis(phenylmethanethiolatotriphenylphosphineplatinum(II))

Guidance literature:: byproducts: triphenylphosphine; the monomer was heated to 200°C in vacuo, the crzstals were melted, effervesced, resolidified, was kept at 200°C. for 15 min; phosphine was distilled into liq. N2, product was extracted in CH2Cl2, recrystd. from CH2Cl2/ether, elem. anal.;
DOI:10.1139/v82-295

Reference yield: 61.0%

: 7764-30-9
2,2'-disulfanediylbis(isoindoline-1,3-dione)

: 75365-64-9
cis-(PPh₃)2Pt(SCH₂Ph)2

: 85882-93-5
cis-(phenylmethanethiolato)(phthalimido)bis(triphenylphosphine)platinum(II)

Guidance literature:: In toluene; soln. stirred at room temp. for 25 h; ppt. filtered, recrystd. (CH2Cl2/Et2O), washed (Et2O), dried for 24 h (vac.);