allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside

Base Information

• Chemical Name: allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside
• CAS No.: 302799-56-0
• Molecular Formula: C₁₁₁H₁₁₂Cl₆O₂₁
• Molecular Weight: 1994.82
• Mol file: 302799-56-0.mol

Synonyms:allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside

Chemical Property of allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside

There total 1 articles about allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

tert-butyl isocyanide (630-18-2) + 3,4,6-tri-O-(p-chlorobenzyl)-α-D-arabino-hexopyranos-2-ulosyl bromide (302799-54-8) + allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside (302799-55-9) → C89H95Cl3O17 + allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside (302799-56-0) + C111H112Cl6O21

Guidance literature:

tert-butyl isocyanide; 3,4,6-tri-O-(p-chlorobenzyl)-α-D-arabino-hexopyranos-2-ulosyl bromide; allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside; With 2,6-di-tert-butyl-4-methylpyridine; silver trifluoromethanesulfonate;

With L-Selectride; In tetrahydrofuran; at -78 ℃;

DOI:10.1021/ol0061743

Reference yield: 74.0%

2-mercaptoethylamine hydrochloride (156-57-0) + allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside (302799-56-0) → 3-(2-aminoethylthio)-propyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside

Guidance literature:

In methanol; dichloromethane; Irradiation;

DOI:10.1021/jo010570x

Reference yield: 51.0%

3,4,6-tri-O-(p-chlorobenzyl)-α-D-arabino-hexopyranos-2-ulosyl bromide (302799-54-8) + allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside (302799-56-0) → C138H137Cl9O26

Guidance literature:

3,4,6-tri-O-(p-chlorobenzyl)-α-D-arabino-hexopyranos-2-ulosyl bromide; allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside; With 2,6-di-tert-butyl-4-methylpyridine; tert-butyl isocyanide; 4 A molecular sieve; In dichloromethane; at 20 ℃; for 0.5h;

With silver trifluoromethanesulfonate; In dichloromethane; at -40 - 20 ℃; for 4h;

With L-Selectride; In tetrahydrofuran; at -78 - 20 ℃; Further stages.;

DOI:10.1021/jo010570x

upstream raw materials:

tert-butyl isocyanide

3,4,6-tri-O-(p-chlorobenzyl)-α-D-arabino-hexopyranos-2-ulosyl bromide

allyl (3,4,6-tri-O-p-chlorobenzyl-β-D-mannopyranosyl)(1->2)(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)(1->2)-3,4,6-tri-O-benzyl-β-D-mannopyranoside