(η6-benzene)bis(triphenylphosphine)iridium(I) hexafluoroantimonate

Base Information

Chemical Name:(η6-benzene)bis(triphenylphosphine)iridium(I) hexafluoroantimonate
CAS No.:94249-80-6
Molecular Formula:C₄₂H₃₆IrP₂*F₆Sb
Molecular Weight:1030.66
Hs Code.:

Synonyms:(η6-benzene)bis(triphenylphosphine)iridium(I) hexafluoroantimonate

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Chemical Property of (η6-benzene)bis(triphenylphosphine)iridium(I) hexafluoroantimonate

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Technology Process of (η6-benzene)bis(triphenylphosphine)iridium(I) hexafluoroantimonate

There total 5 articles about (η6-benzene)bis(triphenylphosphine)iridium(I) hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 110077-68-4,89509-77-3
{IrH₂(acetone)2(PPh₃)2}SbF₆

: 558-37-2
tert-butylethylene

: 94249-80-6
(η6-benzene)bis(triphenylphosphine)iridium(I) hexafluoroantimonate

Guidance literature:: With benzene; In benzene; byproducts: (CH3)3CCH2CH3; (N2), suspn. of the complex in benzene refluxed with an equivalent of tbe for 6 h; cooled, Et2O added, filtered, recrystd. from CH2Cl2/Et2O, elem. anal.;
DOI:10.1021/om00122a015

Reference yield: 45.0%

: 110077-68-4,89509-77-3
{IrH₂(acetone)2(PPh₃)2}SbF₆

: 110-82-7,25012-93-5
cyclohexane

: 94249-80-6
(η6-benzene)bis(triphenylphosphine)iridium(I) hexafluoroantimonate

: 91410-24-1
{(η5-cyclohexadienyl)IrH(PPh3)2}SbF6

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

Guidance literature:: With tert-butylethylene; In neat (no solvent); Ir-complex (grounded to a fine powder) was heated with cyclohexane and t-BuCH=CH2 in a sealed pressure vessel magnetically stirred under inert atmosphere; volatiles removed in vacuo, residue was analysed by (1)H NMR spectroscopy; yield and product ratio depend on the reaction temp.;
DOI:10.1021/om00147a003

Reference yield:

: 91410-24-1
{(η5-cyclohexadienyl)IrH(PPh3)2}SbF6

: 287-92-3
Cyclopentane

: 94249-80-6
(η6-benzene)bis(triphenylphosphine)iridium(I) hexafluoroantimonate

: hydrido(η-cyclopentadienyl)bis(triphenylphosphine)iridium(III) hexafluoroantimonate

Guidance literature:: With tert-butylethylene; In 1,2-dichloro-ethane; byproducts: tert-butylethane, benzene; refluxing (100 °C, 20 h); not isolated; detected 1H NMR spect.;