{(η5-cyclohexadienyl)IrH(PPh3)2}SbF6

Base Information

Chemical Name:{(η5-cyclohexadienyl)IrH(PPh3)2}SbF6
CAS No.:91410-24-1
Molecular Formula:C₄₂H₃₈IrP₂*F₆Sb
Molecular Weight:1032.67
Hs Code.:

Synonyms:{(η5-cyclohexadienyl)IrH(PPh3)2}SbF6

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Chemical Property of {(η5-cyclohexadienyl)IrH(PPh3)2}SbF6

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Technology Process of {(η5-cyclohexadienyl)IrH(PPh3)2}SbF6

There total 6 articles about {(η5-cyclohexadienyl)IrH(PPh3)2}SbF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 91410-27-4
{Ir(COD)(PPh₃)2}SbF₆

: 91410-24-1
{(η5-cyclohexadienyl)IrH(PPh3)2}SbF6

Guidance literature:: With cyclohexa-1,4-diene; hydrogen; In dichloromethane; byproducts: cyclooctane; (N2), compounds dissolved at 0°C, H2 passed through the soln. at0°C for 20 min, soln. swept with Ar, stirred at 4°C for 24 h; slow addn. of Et2O, filtered, recrystd. from CH2Cl2/Et2O, elem. anal.;
DOI:10.1021/om00122a015

Reference yield: 86.0%

: 91410-27-4
{Ir(COD)(PPh₃)2}SbF₆

: 1165952-91-9
cyclohexa-1,3-diene

: 91410-24-1
{(η5-cyclohexadienyl)IrH(PPh3)2}SbF6

Guidance literature:: With hydrogen; In dichloromethane; byproducts: cyclooctane; (N2), compounds dissolved at 0°C, H2 passed through the soln. at0°C for 20 min, soln. swept with Ar, stirred at 4°C for 24 h; slow addn. of Et2O, filtered, recrystd. from CH2Cl2/Et2O, elem. anal.;
DOI:10.1021/om00122a015

Reference yield: 45.0%

: 110077-68-4,89509-77-3
{IrH₂(acetone)2(PPh₃)2}SbF₆

: 110-82-7,25012-93-5
cyclohexane

: 94249-80-6
(η6-benzene)bis(triphenylphosphine)iridium(I) hexafluoroantimonate

: 91410-24-1
{(η5-cyclohexadienyl)IrH(PPh3)2}SbF6

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

Guidance literature:: With tert-butylethylene; In neat (no solvent); Ir-complex (grounded to a fine powder) was heated with cyclohexane and t-BuCH=CH2 in a sealed pressure vessel magnetically stirred under inert atmosphere; volatiles removed in vacuo, residue was analysed by (1)H NMR spectroscopy; yield and product ratio depend on the reaction temp.;
DOI:10.1021/om00147a003