3(C₆H₅CH₂N(C₂H₅)3)⁽¹⁺⁾*(Rh₁₀As(CO)22)^(3-)*OC₄H₈=(C₆H₅CH₂N(C₂H₅)3)3(Rh₁₀As(CO)22)*OC₄H₈

Base Information

• Chemical Name: 3(C₆H₅CH₂N(C₂H₅)3)⁽¹⁺⁾*(Rh₁₀As(CO)22)^(3-)*OC₄H₈=(C₆H₅CH₂N(C₂H₅)3)3(Rh₁₀As(CO)22)*OC₄H₈
• CAS No.: 75802-04-9
• Molecular Formula: C₄H₈O*3C₁₃H₂₂N*C₂₂AsO₂₂Rh₁₀
• Molecular Weight: 2369.29

Synonyms:3(C₆H₅CH₂N(C₂H₅)3)⁽¹⁺⁾*(Rh₁₀As(CO)22)^(3-)*OC₄H₈=(C₆H₅CH₂N(C₂H₅)3)3(Rh₁₀As(CO)22)*OC₄H₈

Chemical Property of 3(C₆H₅CH₂N(C₂H₅)3)⁽¹⁺⁾*(Rh₁₀As(CO)22)^(3-)*OC₄H₈=(C₆H₅CH₂N(C₂H₅)3)3(Rh₁₀As(CO)22)*OC₄H₈

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Technology Process of 3(C₆H₅CH₂N(C₂H₅)3)⁽¹⁺⁾*(Rh₁₀As(CO)22)^(3-)*OC₄H₈=(C₆H₅CH₂N(C₂H₅)3)3(Rh₁₀As(CO)22)*OC₄H₈

There total 2 articles about 3(C₆H₅CH₂N(C₂H₅)3)⁽¹⁺⁾*(Rh₁₀As(CO)22)^(3-)*OC₄H₈=(C₆H₅CH₂N(C₂H₅)3)3(Rh₁₀As(CO)22)*OC₄H₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.8%

acetylacetonatodicarbonylrhodium(l) + triphenyl-arsane (603-32-7) + N-benzyl-N,N,N-triethylammonium chloride (56-37-1) → 3(C6H5CH2N(C2H5)3)(1+)*(Rh10As(CO)22)(3-)*OC4H8=(C6H5CH2N(C2H5)3)3(Rh10As(CO)22)*OC4H8 (75802-04-9)

Guidance literature:

With cesium benzoate trihydrate; cesium borohydride; carbon monoxide; In isopropyl alcohol; acetone; High Pressure; to Rh(CO)2acac, PhCOOCs*3H2O, AsPh3 and CsBH4 mixed in tetraglyme and soln. stirred under 6000 psi CO-H2 at 150°C for 2 h, mixt. filtered, toluene added, oil dissolved in acetone, (PhCH2NEt3)Cl in 2-propanoladded; ppt. filtered, washed with 2-propanol and vac.-dried; elem. anal.;

DOI:10.1021/ic50215a048

Reference yield: 28.8%

acetylacetonatodicarbonylrhodium(l) + triphenyl-arsane (603-32-7) + N-benzyl-N,N,N-triethylammonium chloride (56-37-1) → 2(C6H5CH2N(C2H5)3)(1+)*(Rh9As)(2-)*21CO=(C6H5CH2N(C2H5)3)2(Rh9As(CO)21) (75802-02-7) + 3(C6H5CH2N(C2H5)3)(1+)*(Rh10As(CO)22)(3-)*OC4H8=(C6H5CH2N(C2H5)3)3(Rh10As(CO)22)*OC4H8 (75802-04-9)

Guidance literature:

With cesium benzoate; carbon monoxide; hydrogen; In tetrahydrofuran; isopropyl alcohol; High Pressure; to Rh(CO)2acac and PhCOOCs in CH3(OCH2CH2)4OCH3 AsPh3 added and stirredfor 0.5 h under Ar, soln. stirred under 250 atm CO:H2 (1:1) at 140-160°C overnight, mixt. filtered, toluene added, oil dissolved in THF,(PhCH2NEt3)Cl in 2-propanol added; ppt. filtered, washed with 2-propanol and vac.-dried - (Rh10As(CO)22)(3-); mother liquor treated with hexane, ppt. filtered, washed with 2-propnol and vac.-dried - (Rh9As(CO)21)(2-); elem. anal.;

DOI:10.1021/ic50215a048

Reference yield:

3(C6H5CH2N(C2H5)3)(1+)*(Rh10As(CO)22)(3-)*OC4H8=(C6H5CH2N(C2H5)3)3(Rh10As(CO)22)*OC4H8 (75802-04-9) + [13C]Carbon monoxide (1641-69-6) → 3(C6H5CH2N(C2H5)3)(1+)*(Rh10As(CO)22)(3-)=(C6H5CH2N(C2H5)3)3(Rh10As(CO)22)

Guidance literature:

In not given; (PhCH2N(C2H5)3)3(Rh10As(CO)22) enriched for 72 h at 25°C under 1atm 50% carbon-13 monoxide;

DOI:10.1021/ic50215a048

upstream raw materials:

triphenyl-arsane

N-benzyl-N,N,N-triethylammonium chloride

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