Carbon monoxide (13C)

Base Information

• Chemical Name: Carbon monoxide (13C)
• CAS No.: 1641-69-6
• Molecular Formula: CO
• Molecular Weight: 28.9994
• European Community (EC) Number: 683-582-4
• DSSTox Substance ID: DTXSID70430693
• Nikkaji Number: J1.953.777C
• Wikidata: Q82244372
• Mol file: 1641-69-6.mol

Synonyms:CARBON MONOXIDE (13C);1641-69-6;Carbon-13C monoxide;(113C)methylidyneoxidanium;DTXSID70430693;Carbon-13C monoxide, <5 atom % 18O, 99 atom % 13C

Chemical Property of Carbon monoxide (13C)

Chemical Property:

• Melting Point: ?207?°C(lit.)
• Density: 1.25?g/mL?at 25?°C(lit.)
• XLogP3: 0.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 28.998269455
• Heavy Atom Count: 2
• Complexity: 10

Purity/Quality:

98% ^*data from raw suppliers

CARBON-13C MONOXIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,F+
• Statements: 61-12-23-48/23
• Safety Statements: 53-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[O+]
• Isomeric SMILES: [13C-]#[O+]

Technology Process of Carbon monoxide (13C)

There total 47 articles about Carbon monoxide (13C) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

C14(13)CH10O (1202553-62-5) → [13C]Carbon monoxide (1641-69-6) + benzil (134-81-6)

Guidance literature:

With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; water; copper(ll) bromide; palladium dichloride; In 1,4-dioxane; for 36h; Schlenk technique; Heating;

DOI:10.1002/cjoc.202000040

Reference yield:

triethanolamine (102-71-6,64114-46-1) + carbon dioxide (1111-72-4) → hydrogen (1333-74-0) + [13C]Carbon monoxide (1641-69-6)

Guidance literature:

With Re-Bpy-sp2c-COF; In acetonitrile; Irradiation;

DOI:10.1039/c9sc03800k

Reference yield:

[13C]methanol (14742-26-8) → methane (6532-48-5) + [13C]-formaldehyde (3228-27-1,89277-65-6) + [1,2-13C2]-glycolaldehyde (478529-69-0,478529-67-8) + ketene + (13C)-methyl formate + carbon dioxide (1111-72-4) + [13C]Carbon monoxide (1641-69-6) + ethylene glycol-13C2 (104700-12-1) + 13C-carbon monoxide + (13)CH2OH

Guidance literature:

at -267.66 - 26.84 ℃; Irradiation;

DOI:10.1039/c4cp04149f

upstream raw materials:

carbon dioxide

bis(pinacol)diborane

carbonylbis(η5-(methyl)5cyclopentadienyl)vanadium(II)

carbon dioxide

Downstream raw materials:

n-decanoic acid-1-¹³C

acetophenone-13C=O

⁽¹³⁾C-benzaldehyde

1-(13C)benzoic acid

Refernces

• 1、 Yang, Wenhong,Dong, Yujing,Wang, Zhipeng,Li, Yuqin,Dai, Chunhui,Ma, Dongwei,Jia, Yu,Yang, Zhen,Zeng, Chao. "Synthesis, characterization, and photocatalytic activity of stannum-doped MgIn2S4 microspheres". . . Retrieved 2021.
• 2、 Narouz, Mina R.,Osten, Kimberly M.,Unsworth, Phillip J.,Man, Renee W. Y.,Salorinne, Kirsi,Takano, Shinjiro,Tomihara, Ryohei,Kaappa, Sami,Malola, Sami,Dinh, Cao-Thang,Padmos, J. Daniel,Ayoo, Kennedy,Garrett, Patrick J.,Nambo, Masakazu,Horton, J. Hugh,Sargent, Edward H.,H?kkinen, Hannu,Tsukuda, Tatsuya,Crudden, Cathleen M.. "N-heterocyclic carbene-functionalized magic-number gold nanoclusters". . p. 419 - 425. Retrieved 2019.
• 3、 Kuo, Hsin-Ya,Lee, Tia S.,Chu, An T.,Tignor, Steven E.,Scholes, Gregory D.,Bocarsly, Andrew B.. "A cyanide-bridged di-manganese carbonyl complex that photochemically reduces CO2 to CO". . p. 1226 - 1236. Retrieved 2019.
• 4、 Zhou, Jie,Wu, Han,Sun, Chun-Yi,Hu, Cheng-Ying,Wang, Xin-Long,Kang, Zhen-Hui,Su, Zhong-Min. "Ultrasmall C-TiO2?x nanoparticle/g-C3N4 composite for CO2 photoreduction with high efficiency and selectivity". . p. 21596 - 21604. Retrieved 2018.
• 5、 Hua, Shao-An,Paul, Lucas A.,Oelschlegel, Manuel,Dechert, Sebastian,Meyer, Franc,Siewert, Inke. "A Bioinspired Disulfide/Dithiol Redox Switch in a Rhenium Complex as Proton, H Atom, and Hydride Transfer Reagent". . p. 6238 - 6247. Retrieved 2021.
• 6、 Kuehnel, Moritz F.,Orchard, Katherine L.,Dalle, Kristian E.,Reisner, Erwin. "Selective Photocatalytic CO2 Reduction in Water through Anchoring of a Molecular Ni Catalyst on CdS Nanocrystals". . p. 7217 - 7223. Retrieved 2017.
• 7、 Choi, Ji Yong,Lim, Chan Kyu,Park, Bumjin,Kim, Minjun,Jamal, Aqil,Song, Hyunjoon. "Surface activation of cobalt oxide nanoparticles for photocatalytic carbon dioxide reduction to methane". . p. 15068 - 15072. Retrieved 2019.
• 8、 Shankar, Ravi,Sachs, Michael,Francàs, Laia,Lubert-Perquel, Daphné,Kerherve, Gwilherm,Regoutz, Anna,Petit, Camille. "Porous boron nitride for combined CO2 capture and photoreduction". . p. 23931 - 23940. Retrieved 2019.
• 9、 Fu, Zi-Cheng,Xu, Rong-Chen,Moore, Joshua T.,Liang, Fei,Nie, Xiao-Cun,Mi, Chen,Mo, Jiang,Xu, Yong,Xu, Quan-Qing,Yang, Zhi,Lin, Zhe-Shuai,Fu, Wen-Fu. "Highly Efficient Photocatalytic System Constructed from CoP/Carbon Nanotubes or Graphene for Visible-Light-Driven CO2 Reduction". . p. 4273 - 4278. Retrieved 2018.
• 10、 Li, Yingxuan,Wen, Miaomiao,Wang, Ying,Tian, Guang,Wang, Chuanyi,Zhao, Jincai. "Plasmonic Hot Electrons from Oxygen Vacancies for Infrared Light-Driven Catalytic CO2 Reduction on Bi2O3?x". . p. 910 - 916. Retrieved 2021.