methyl 4-S-benzoyl-3-O-tertbutyldimethylsilyl-2,6-dideoxy-4-thio-α-D-arabino-hexopyranoside

Base Information

Chemical Name:methyl 4-S-benzoyl-3-O-tertbutyldimethylsilyl-2,6-dideoxy-4-thio-α-D-arabino-hexopyranoside
CAS No.:152870-50-3
Molecular Formula:C₂₀H₃₂O₄SSi
Molecular Weight:396.623
Hs Code.:

Synonyms:methyl 4-S-benzoyl-3-O-tertbutyldimethylsilyl-2,6-dideoxy-4-thio-α-D-arabino-hexopyranoside

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Chemical Property of methyl 4-S-benzoyl-3-O-tertbutyldimethylsilyl-2,6-dideoxy-4-thio-α-D-arabino-hexopyranoside

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Technology Process of methyl 4-S-benzoyl-3-O-tertbutyldimethylsilyl-2,6-dideoxy-4-thio-α-D-arabino-hexopyranoside

There total 4 articles about methyl 4-S-benzoyl-3-O-tertbutyldimethylsilyl-2,6-dideoxy-4-thio-α-D-arabino-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 28170-13-0
thiobenzoic acid potassium salt

: Trifluoro-methanesulfonic acid (2R,3S,4R,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester

: 152870-50-3
methyl 4-S-benzoyl-3-O-tertbutyldimethylsilyl-2,6-dideoxy-4-thio-α-D-arabino-hexopyranoside

Guidance literature:: In N,N-dimethyl-formamide; for 4h; Ambient temperature;
DOI:10.1016/0040-4020(95)00059-H

Reference yield:

: 134355-03-6
6-deoxy-D-glucal

: 152870-50-3
methyl 4-S-benzoyl-3-O-tertbutyldimethylsilyl-2,6-dideoxy-4-thio-α-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / camphorsulfonic acid / Ambient temperature

3: pyridine / CH₂Cl₂ / 0 °C

4: dimethylformamide / 0 °C

With pyridine; camphor-10-sulfonic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/0040-4039(93)88072-Q

Reference yield:

: 152870-48-9
methyl 3-O-tertbutyldimethylsilyl-2,6-dideoxy-α-D-lyxo-pyranoside

: 152870-50-3
methyl 4-S-benzoyl-3-O-tertbutyldimethylsilyl-2,6-dideoxy-4-thio-α-D-arabino-hexopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / CH₂Cl₂ / 0 °C

2: dimethylformamide / 0 °C

With pyridine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/0040-4039(93)88072-Q