tert-Butyl-dimethyl-((E)-1-phenylsulfanyl-propenyloxy)-silane

Base Information

• Chemical Name: tert-Butyl-dimethyl-((E)-1-phenylsulfanyl-propenyloxy)-silane
• CAS No.: 117481-61-5
• Molecular Formula: C₁₅H₂₄OSSi
• Molecular Weight: 280.506
• Mol file: 117481-61-5.mol

Synonyms:tert-Butyl-dimethyl-((E)-1-phenylsulfanyl-propenyloxy)-silane

Chemical Property of tert-Butyl-dimethyl-((E)-1-phenylsulfanyl-propenyloxy)-silane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tert-Butyl-dimethyl-((E)-1-phenylsulfanyl-propenyloxy)-silane

There total 1 articles about tert-Butyl-dimethyl-((E)-1-phenylsulfanyl-propenyloxy)-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

S-phenylthiopropionate (18245-72-2) + tert-butyldimethylsilyl chloride (18162-48-6) → tert-Butyl-dimethyl-((E)-1-phenylsulfanyl-propenyloxy)-silane (117481-61-5)

Guidance literature:

With N,N-dimethyl-formamide; lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃;

DOI:10.1016/0040-4039(95)01231-6

Reference yield: 47.0%

ethyl (4-methoxyphenylimino)acetate (124156-21-4) + tert-Butyl-dimethyl-((E)-1-phenylsulfanyl-propenyloxy)-silane (117481-61-5) → C20H23NO4S

Guidance literature:

With scandium tris(trifluoromethanesulfonate); In water; at 20 ℃;

DOI:10.1016/j.jorganchem.2007.10.013

Reference yield: 22.0%

4-nitrobenzaldehdye (555-16-8) + tert-Butyl-dimethyl-((E)-1-phenylsulfanyl-propenyloxy)-silane (117481-61-5) → C19H25NO3SSi (1356131-85-5) + C22H29NO4SSi + 3-methyl-4-(4-nitro-phenyl)-oxetan-2-one

Guidance literature:

With zinc(II) chloride; In dichloromethane; at 23 ℃; Inert atmosphere;

DOI:10.1021/ja209163w

upstream raw materials:

S-phenylthiopropionate

tert-butyldimethylsilyl chloride

Downstream raw materials:

anti-S-phenyl 3-hydroxy-2-methyl-3-phenylpropanethioate

syn-S-phenyl 3-hydroxy-2-methyl-3-phenylpropanethioate

C₁₇H₁₇NO₄S

C₁₂H₁₄O₂