p-methoxyphenyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-erythro-hex-3-enopyranoside

Base Information

Chemical Name:p-methoxyphenyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-erythro-hex-3-enopyranoside
CAS No.:400054-06-0
Molecular Formula:C₁₉H₃₀O₅Si
Molecular Weight:366.53
Hs Code.:

Synonyms:p-methoxyphenyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-erythro-hex-3-enopyranoside

Suppliers and Price of p-methoxyphenyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-erythro-hex-3-enopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of p-methoxyphenyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-erythro-hex-3-enopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of p-methoxyphenyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-erythro-hex-3-enopyranoside

There total 6 articles about p-methoxyphenyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-erythro-hex-3-enopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 400054-04-8
p-methoxyphenyl 3,4-dideoxy-α-D-erythro-hex-3-enopyranoside

: 400054-06-0
p-methoxyphenyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-erythro-hex-3-enopyranoside

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 20 ℃;
DOI:10.1002/chem.200305358

Reference yield:

: 400054-02-6
p-methoxyphenyl 2,4,6-triacetyl-3-deoxy-α-D-erythro-hex-2-enopyranoside

: 400054-06-0
p-methoxyphenyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-erythro-hex-3-enopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / LiAlH₄ / tetrahydrofuran / 1 h / 0 °C

2: 75 percent / Et₃N; 4-dimethylaminopyridine / CH₂Cl₂ / 20 °C

With dmap; lithium aluminium tetrahydride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1002/chem.200305358

Reference yield:

: 3366-47-0
2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-arabinohex-1-enopyranose

: 400054-06-0
p-methoxyphenyl 6-O-(tert-butyldimethylsilyl)-3,4-dideoxy-α-D-erythro-hex-3-enopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 49 percent / BF₃*OEt₂ / benzene / 20 °C

2: 84 percent / LiAlH₄ / tetrahydrofuran / 1 h / 0 °C

3: 75 percent / Et₃N; 4-dimethylaminopyridine / CH₂Cl₂ / 20 °C

With dmap; lithium aluminium tetrahydride; boron trifluoride diethyl etherate; triethylamine; In tetrahydrofuran; dichloromethane; benzene;
DOI:10.1002/chem.200305358