2,2'-Diisopropylbiphenyl

Base Information

Chemical Name:2,2'-Diisopropylbiphenyl
CAS No.:36919-88-7
Molecular Formula:C₁₈H₂₂
Molecular Weight:238.373
Hs Code.:
Mol file:36919-88-7.mol

Synonyms:2,2'-diisopropyl-1,1'-biphenyl;bis(methylethyl)-1,1'-biphenyl;2,2'-Diiisopropylbiphenyl;2,2'-Diisopropylbiphenyl;2,2'-Diisopropyl-biphenyl;diisopropylbiphenyl;

Suppliers and Price of 2,2'-Diisopropylbiphenyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 2,2'-Diisopropylbiphenyl

Chemical Property:

PSA：0.00000
LogP:5.60040

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,2'-Diisopropylbiphenyl

There total 5 articles about 2,2'-Diisopropylbiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: 89787-12-2
2-isopropylphenylboronic acid

: 54845-36-2
2-chloro-1,3-bis(1-methylethyl)benzene

: 99-62-7
1,3-diisopropylbenzene

: 36919-88-7,151378-45-9,151378-46-0
2,2′-diisopropylbiphenyl

: 1482498-20-3
2,2',6-trisopropylbiphenyl

Guidance literature:: With potassium phosphate monohydrate; Ethyl 4-bromobenzoate; C₅₂H₄₉PRu; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In 1,4-dioxane; at 100 ℃; for 4.5h; Inert atmosphere;
DOI:10.1021/jo402089r

Reference yield:

: 92-52-4,1594-86-1
biphenyl

: 187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4
propene

: 2,3'-diisopropyl-1,1'-biphenyl

: 7116-95-2
4-isopropylbiphenyl

: 19486-60-3
2-isopropylbiphenyl

: 36919-88-7,151378-45-9,151378-46-0
2,2′-diisopropylbiphenyl

: 18970-30-4
4,4' diisopropylbiphenyl

: 61434-46-6
3,4'-di-isopropylbiphenyl

: 61434-45-5
2,4'-diisopropylbiphenyl

: 20282-30-8
m-mono-isopropylbiphenyl

: 69375-12-8
3,3'-di-isopropylbiphenyl

Guidance literature:: With silica-alumina; at 300 ℃; under 7500.75 Torr; Reagent/catalyst; Time; Autoclave;
DOI:10.1016/j.apcata.2012.12.011

Reference yield:

: 24544-04-5
2,6-diisopropylbenzenamine

: 99-62-7
1,3-diisopropylbenzene

: 36919-88-7,151378-45-9,151378-46-0
2,2′-diisopropylbiphenyl

: 1482498-20-3
2,2',6-trisopropylbiphenyl

Guidance literature:: Multi-step reaction with 2 steps

1.1: hydrogenchloride; sodium nitrite / water; ethanol / 1 h / 0 °C / Inert atmosphere

1.2: 0.83 h / Inert atmosphere; Reflux

2.1: C₅₂H₄₉PRu; potassium phosphate monohydrate; bis(dibenzylideneacetone)-palladium⁽⁰⁾; Ethyl 4-bromobenzoate / 1,4-dioxane / 4.5 h / 100 °C / Inert atmosphere

With hydrogenchloride; potassium phosphate monohydrate; Ethyl 4-bromobenzoate; C₅₂H₄₉PRu; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium nitrite; In 1,4-dioxane; ethanol; water; 2.1: |Suzuki-Miyaura Coupling;
DOI:10.1021/jo402089r