[5,15-bis(3',5'-di-tert-butylphenyl)-10-trimethylsilylethynylporphyrinato]zinc(II)

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Chemical Name:[5,15-bis(3',5'-di-tert-butylphenyl)-10-trimethylsilylethynylporphyrinato]zinc(II)
CAS No.:294183-85-0
Molecular Formula:C₅₃H₆₀N₄SiZn
Molecular Weight:846.562
Hs Code.:

Synonyms:[5,15-bis(3',5'-di-tert-butylphenyl)-10-trimethylsilylethynylporphyrinato]zinc(II)

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Chemical Property of [5,15-bis(3',5'-di-tert-butylphenyl)-10-trimethylsilylethynylporphyrinato]zinc(II)

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Technology Process of [5,15-bis(3',5'-di-tert-butylphenyl)-10-trimethylsilylethynylporphyrinato]zinc(II)

There total 1 articles about [5,15-bis(3',5'-di-tert-butylphenyl)-10-trimethylsilylethynylporphyrinato]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 294183-84-9
[5,15-bis(3',5'-di-tert-butylphenyl)-10-bromoporphyrinato]zinc(II)

: 1066-54-2
trimethylsilylacetylene

: 294183-85-0
[5,15-bis(3',5'-di-tert-butylphenyl)-10-trimethylsilylethynylporphyrinato]zinc(II)

Guidance literature:: With Pd₂(dibenzylideneacetone)3/PPh₃; CuI; Et₃N/C₅H₅N; In pyridine; triethylamine; toluene; Bromoporphyrin, Pd compd., PPh3, CuI were dried (vac.) and dissolved in toluene, pyridine and Et3N; soln. was degassed; Me3SiCCH was added; mixt. was stirred at 45°C for 15 h under inert atm; washed (water); org. phase evapd.; chromd. (SiO2, petroleum ether/EtOAc/pyridine, 10/1/0.1); crystd. (CHCl3/1% water-methanol);
DOI:10.1039/b109915a

Reference yield: 91.0%

: 294183-85-0
[5,15-bis(3',5'-di-tert-butylphenyl)-10-trimethylsilylethynylporphyrinato]zinc(II)

: 294183-82-7
[5-ethynyl-10,20-bis[3',5'-(di-tert-butyl)phenyl]porphinato]zinc(II)

Guidance literature:: With Bu₄NF; In tetrahydrofuran; dichloromethane; soln. of Bu4NF in THF was added to soln. of Zn complex in CH2Cl2; mixt. was stirred at room temp. for 15 min; CH3COOH added; pptd. with 1% water in methanol;
DOI:10.1039/b109915a