Technology Process of 2,2,6,6-tetramethyl-1-(2-methyl-1-(4-(((6-(triethoxysilyl)hexyl)oxy)methyl)phenyl)propoxy)piperidine
There total 7 articles about 2,2,6,6-tetramethyl-1-(2-methyl-1-(4-(((6-(triethoxysilyl)hexyl)oxy)methyl)phenyl)propoxy)piperidine which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex;
at 50 ℃;
for 6h;
Sealed tube;
DOI:10.1002/chem.201200499
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: hydrogen bromide; acetic acid / dichloromethane / 14 h / 0 - 20 °C
2.1: copper; copper(II) bis(trifluoromethanesulfonate); 4,4'-di-tert-butyl-2,2'-bipyridine / benzene / 28 h / 80 °C
3.1: lithium aluminium tetrahydride / tetrahydrofuran / 1.5 h / 20 °C
4.1: sodium iodide; chloro-trimethyl-silane / acetonitrile / 6 h / 20 °C
5.1: sodium hydride / mineral oil; tetrahydrofuran / 2 h / 70 °C
5.2: 30 h / 70 °C
6.1: platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex / 6 h / 50 °C / Sealed tube
With
lithium aluminium tetrahydride; chloro-trimethyl-silane; platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; hydrogen bromide; copper(II) bis(trifluoromethanesulfonate); copper; sodium hydride; acetic acid; 4,4'-di-tert-butyl-2,2'-bipyridine; sodium iodide;
In
tetrahydrofuran; dichloromethane; acetonitrile; mineral oil; benzene;
DOI:10.1002/chem.201200499
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: copper; copper(II) bis(trifluoromethanesulfonate); 4,4'-di-tert-butyl-2,2'-bipyridine / benzene / 28 h / 80 °C
2.1: lithium aluminium tetrahydride / tetrahydrofuran / 1.5 h / 20 °C
3.1: sodium iodide; chloro-trimethyl-silane / acetonitrile / 6 h / 20 °C
4.1: sodium hydride / mineral oil; tetrahydrofuran / 2 h / 70 °C
4.2: 30 h / 70 °C
5.1: platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex / 6 h / 50 °C / Sealed tube
With
lithium aluminium tetrahydride; chloro-trimethyl-silane; platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; copper(II) bis(trifluoromethanesulfonate); copper; sodium hydride; 4,4'-di-tert-butyl-2,2'-bipyridine; sodium iodide;
In
tetrahydrofuran; acetonitrile; mineral oil; benzene;
DOI:10.1002/chem.201200499
