1-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-7-methyl-oct-4-yn-3-one

Base Information

Chemical Name:1-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-7-methyl-oct-4-yn-3-one
CAS No.:932699-75-7
Molecular Formula:C₄₈H₆₆O₄Si₃
Molecular Weight:791.306
Hs Code.:

1-(<i>tert</i>-butyl-dimethyl-silanyloxy)-8-(<i>tert</i>-butyl-diphenyl-silanyloxy)-7-(<i>tert</i>-butyl-diphenyl-silanyloxymethyl)-7-methyl-oct-4-yn-3-one

Synonyms:1-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-7-methyl-oct-4-yn-3-one

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Chemical Property of 1-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-7-methyl-oct-4-yn-3-one

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Technology Process of 1-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-7-methyl-oct-4-yn-3-one

There total 5 articles about 1-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-7-methyl-oct-4-yn-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 932699-74-6
3-(tert-butyl-dimethyl-silanyloxy)-N-methoxy-N-methyl-propionamide

: 932699-73-5
C₃₉H₄₈O₂Si₂

: 932699-75-7
1-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-7-methyl-oct-4-yn-3-one

Guidance literature:: With n-butyllithium; In diethyl ether; at -78 - -30 ℃; for 12h;
DOI:10.1021/ol063087n

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 932699-75-7
1-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-7-methyl-oct-4-yn-3-one

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole; DMAP / CH₂Cl₂ / 20 °C

2: 9.87 g / i-PrMgCl / tetrahydrofuran / -20 - -15 °C

3: 90 percent / n-BuLi / diethyl ether / 12 h / -78 - -30 °C

With 1H-imidazole; dmap; n-butyllithium; isopropylmagnesium chloride; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ol063087n

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 932699-75-7
1-(tert-butyl-dimethyl-silanyloxy)-8-(tert-butyl-diphenyl-silanyloxy)-7-(tert-butyl-diphenyl-silanyloxymethyl)-7-methyl-oct-4-yn-3-one

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / imidazole; DMAP / CH₂Cl₂ / 0 - 20 °C

2: 90 percent / n-BuLi / diethyl ether / 12 h / -78 - -30 °C

With 1H-imidazole; dmap; n-butyllithium; In diethyl ether; dichloromethane;
DOI:10.1021/ol063087n