11-Methoxy-3,7,11-trimethyldodeca-2,4-dienoic acid

Base Information

• Chemical Name: 11-Methoxy-3,7,11-trimethyldodeca-2,4-dienoic acid
• CAS No.: 53023-65-7
• Molecular Formula: C16H28O3
• Molecular Weight: 268.397
• European Community (EC) Number: 258-305-1
• Wikidata: Q27163507
• Mol file: 53023-65-7.mol

Synonyms:11-methoxy-3,7,11-trimethyldodeca-2,4-dienoic acid;53023-65-7;C16H28O3;EINECS 258-305-1;2,4-Dodecadienoic acid, 11-methoxy-3,7,11-trimethyl-, (2Z,4E)-;CBiol_001854;KBioGR_000136;KBioSS_000136;(+-)-(2Z,4E)-11-Methoxy-3,7,11-trimethyl-2,4-dodecadienoic acid;(2E,4E)-(+-)-11-methoxy-3,7,11-trimethyldodeca-2,4-dienoic acid;(2E,4E)-11-METHOXY-3,7,11-TRIMETHYLDODECA-2,4-DIENOIC ACID;2,4-Dodecadienoic acid, 11-methoxy-3,7,11-trimethyl-, (E,E)-(.+.)-;KBio2_000136;KBio2_002704;KBio2_005272;KBio3_000271;KBio3_000272;MNYBEULOKRVZKY-UHFFFAOYSA-N;Bio1_000140;Bio1_000629;Bio1_001118;Bio2_000136;Bio2_000616;Q27163507;2,4-Dodecadienoic acid, 11-methoxy-3,7,11-trimethyl-, (Z,E)-;(2Z,4E)-(+-)-11-methoxy-3,7,11-trimethyldodeca-2,4-dienoic acid;2,4-Dodecadienoic acid, 11-methoxy-3,7,11-trimethyl-, (Z,E)-(.+.)-

Chemical Property of 11-Methoxy-3,7,11-trimethyldodeca-2,4-dienoic acid

Chemical Property:

• Vapor Pressure: 2.62E-07mmHg at 25°C
• Boiling Point: 394.1°C at 760 mmHg
• Flash Point: 134.2°C
• Density: 0.954g/cm³
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 9
• Exact Mass: 268.20384475
• Heavy Atom Count: 19
• Complexity: 327

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(CCCC(C)(C)OC)CC=CC(=CC(=O)O)C

Technology Process of 11-Methoxy-3,7,11-trimethyldodeca-2,4-dienoic acid

There total 3 articles about 11-Methoxy-3,7,11-trimethyldodeca-2,4-dienoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

6-(6-Methoxy-2,6-dimethyl-heptyl)-4-methyl-3,6-dihydro-pyran-2-one (52313-82-3) → (2Z,4E)-11-methoxy-3,7,11-trimethyl-dodeca-2,4-dienoic acid (53023-65-7,207597-76-0)

Guidance literature:

With sodium ethanolate; In ethanol;

DOI:10.1021/jo00889a001

Reference yield:

→ S-(4E)-3,7,11-Trimethyl-11-methoxy-2,4-dodecadiensaeure (40596-67-6,41915-75-7,53023-65-7,53092-52-7,56374-19-7,84889-18-9,207597-76-0)

Guidance literature:

S-(-)-7-Methoxydihydrocitronellal, Diisopropyl-3-isopropoxycarbonyl-2-methyl-2-propenylphosphonat, NaH;

DOI:10.1021/jf60217a019

Reference yield:

→ R-(4E)-3,7,11-Trimethyl-11-methoxy-2,4-dodecadiensaeure (40596-67-6,41915-75-7,53023-65-7,53092-52-7,56374-19-7,84889-18-9,207597-76-0)

Guidance literature:

R-(+)-7-Methoxydihydrocitronellal, Diisopropyl-3-isopropoxycarbonyl-2-methyl-2-propenylphosphonat, NaH;

DOI:10.1021/jf60217a019

upstream raw materials:

6-(6-Methoxy-2,6-dimethyl-heptyl)-4-methyl-3,6-dihydro-pyran-2-one

Downstream raw materials:

Methoprene acid

methoprene