(R)-1-acetoxy-3-(tert-butyl)dimethylsilyloxy-2-((3-bromophenoxy)methyl)propane

Base Information

Chemical Name:(R)-1-acetoxy-3-(tert-butyl)dimethylsilyloxy-2-((3-bromophenoxy)methyl)propane
CAS No.:1357622-32-2
Molecular Formula:C₁₈H₂₉BrO₄Si
Molecular Weight:417.415
Hs Code.:

Synonyms:(R)-1-acetoxy-3-(tert-butyl)dimethylsilyloxy-2-((3-bromophenoxy)methyl)propane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-1-acetoxy-3-(tert-butyl)dimethylsilyloxy-2-((3-bromophenoxy)methyl)propane

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Technology Process of (R)-1-acetoxy-3-(tert-butyl)dimethylsilyloxy-2-((3-bromophenoxy)methyl)propane

There total 5 articles about (R)-1-acetoxy-3-(tert-butyl)dimethylsilyloxy-2-((3-bromophenoxy)methyl)propane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1357622-27-5
(R)-3-acetoxy-2-((3-bromophenoxy)methyl)propanol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1357622-32-2
(R)-1-acetoxy-3-(tert-butyl)dimethylsilyloxy-2-((3-bromophenoxy)methyl)propane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere;
DOI:10.1039/c1ob06632c

Reference yield:

: 1357622-26-4
(R,E)-2-(3-bromophenoxy)methyl-5-methylhex-3-enyl acetate

: 1357622-32-2
(R)-1-acetoxy-3-(tert-butyl)dimethylsilyloxy-2-((3-bromophenoxy)methyl)propane

Guidance literature:: Multi-step reaction with 3 steps

1.1: ozone / methanol; dichloromethane / 0.67 h / -78 °C / Inert atmosphere

1.2: -78 °C / Inert atmosphere

2.1: sodium tetrahydroborate / methanol; dichloromethane / 2.5 h / -78 - -3 °C / Inert atmosphere

3.1: 1H-imidazole / N,N-dimethyl-formamide / 20 °C / Inert atmosphere

With 1H-imidazole; sodium tetrahydroborate; ozone; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/c1ob06632c

Reference yield:

: C₁₂H₁₃BrO₄

: 1357622-32-2
(R)-1-acetoxy-3-(tert-butyl)dimethylsilyloxy-2-((3-bromophenoxy)methyl)propane

Guidance literature:: Multi-step reaction with 2 steps

1: sodium tetrahydroborate / methanol; dichloromethane / 2.5 h / -78 - -3 °C / Inert atmosphere

2: 1H-imidazole / N,N-dimethyl-formamide / 20 °C / Inert atmosphere

With 1H-imidazole; sodium tetrahydroborate; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/c1ob06632c