(E)-N,N'-(2-(phenyldiazenyl)-1,3-phenylene)bis(4-methylbenzenesulfonamide)

Base Information

• Chemical Name: (E)-N,N'-(2-(phenyldiazenyl)-1,3-phenylene)bis(4-methylbenzenesulfonamide)
• CAS No.: 1584667-73-1
• Molecular Formula: C₂₆H₂₄N₄O₄S₂
• Molecular Weight: 520.633
• Mol file: 1584667-73-1.mol

Synonyms:(E)-N,N'-(2-(phenyldiazenyl)-1,3-phenylene)bis(4-methylbenzenesulfonamide)

Chemical Property of (E)-N,N'-(2-(phenyldiazenyl)-1,3-phenylene)bis(4-methylbenzenesulfonamide)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-N,N'-(2-(phenyldiazenyl)-1,3-phenylene)bis(4-methylbenzenesulfonamide)

There total 2 articles about (E)-N,N'-(2-(phenyldiazenyl)-1,3-phenylene)bis(4-methylbenzenesulfonamide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

4-toluenesulfonyl azide (941-55-9) + trans-azobenzene (17082-12-1) → (E)-4-methyl-N-(2-(phenyldiazenyl)phenyl)benzenesulfonamide (1584667-72-0) + (E)-N,N'-(2-(phenyldiazenyl)-1,3-phenylene)bis(4-methylbenzenesulfonamide) (1584667-73-1)

Guidance literature:

With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver(I) triflimide; In 1,2-dichloro-ethane; at 90 ℃; for 12h; Reagent/catalyst; Solvent; Temperature;

DOI:10.1021/ol501250t

Reference yield:

p-toluenesulfonyl chloride (98-59-9) → (E)-4-methyl-N-(2-(phenyldiazenyl)phenyl)benzenesulfonamide (1584667-72-0) + (E)-N,N'-(2-(phenyldiazenyl)-1,3-phenylene)bis(4-methylbenzenesulfonamide) (1584667-73-1)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium azide / acetone; water / 3 h / 0 - 23 °C

2: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver(I) triflimide / 1,2-dichloro-ethane / 12 h / 90 °C

With sodium azide; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver(I) triflimide; In water; 1,2-dichloro-ethane; acetone;

DOI:10.1021/ol501250t

upstream raw materials:

4-toluenesulfonyl azide

trans-azobenzene

p-toluenesulfonyl chloride