Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-3-hydroxy-7-methoxy-2,6,10-trimethyl-undecyl ester

Base Information

Chemical Name:Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-3-hydroxy-7-methoxy-2,6,10-trimethyl-undecyl ester
CAS No.:740836-31-1
Molecular Formula:C₅₅H₇₉NO₇Si₂
Molecular Weight:922.406
Hs Code.:

Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-3-hydroxy-7-methoxy-2,6,10-trimethyl-undecyl ester

Synonyms:Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-3-hydroxy-7-methoxy-2,6,10-trimethyl-undecyl ester

Suppliers and Price of Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-3-hydroxy-7-methoxy-2,6,10-trimethyl-undecyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-3-hydroxy-7-methoxy-2,6,10-trimethyl-undecyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-3-hydroxy-7-methoxy-2,6,10-trimethyl-undecyl ester

There total 4 articles about Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-3-hydroxy-7-methoxy-2,6,10-trimethyl-undecyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 740836-15-1
Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-3-(3,4-dimethoxy-benzyloxymethoxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-7-methoxy-2,6,10-trimethyl-undecyl ester

: 740836-31-1
Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-3-hydroxy-7-methoxy-2,6,10-trimethyl-undecyl ester

Guidance literature:: With phosphate buffer; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; tert-butyl alcohol; at 0 - 20 ℃;
DOI:10.1016/j.tet.2006.06.046

Reference yield:

: 740836-14-0
Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-3-(3,4-dimethoxy-benzyloxymethoxy)-1-((R)-3-hydroxy-1-methyl-propyl)-7-methoxy-2,6,10-trimethyl-undecyl ester

: 740836-31-1
Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-3-hydroxy-7-methoxy-2,6,10-trimethyl-undecyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 20 °C

2: 55 percent / hydroquinone; pyridinium p-toluenesulfonate; molecular sieves 3 Angstroem / benzene / 5 h / Heating

3: 90 percent / 2,3-dichloro-5,6-dicyano-p-benzoquinone; phosphate buffer / CH₂Cl₂; 2-methyl-propan-2-ol / 0 - 20 °C

With phosphate buffer; 3 A molecular sieve; pyridinium p-toluenesulfonate; Dess-Martin periodane; hydroquinone; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; tert-butyl alcohol; benzene;
DOI:10.1016/j.tet.2006.06.046

Reference yield:

: 909803-75-4
Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-3-(3,4-dimethoxy-benzyloxymethoxy)-7-methoxy-2,6,10-trimethyl-1-((R)-1-methyl-3-trityloxy-propyl)-undecyl ester

: 740836-31-1
Acetic acid (1R,2S,3R,6S,7S,9S,10R)-9,11-bis-(tert-butyl-diphenyl-silanyloxy)-1-[(E)-(R)-3-(formyl-methyl-amino)-1-methyl-allyl]-3-hydroxy-7-methoxy-2,6,10-trimethyl-undecyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 77 percent / formic acid / diethyl ether / 0.25 h / 23 °C

2: 91 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 20 °C

3: 55 percent / hydroquinone; pyridinium p-toluenesulfonate; molecular sieves 3 Angstroem / benzene / 5 h / Heating

4: 90 percent / 2,3-dichloro-5,6-dicyano-p-benzoquinone; phosphate buffer / CH₂Cl₂; 2-methyl-propan-2-ol / 0 - 20 °C

With formic acid; phosphate buffer; 3 A molecular sieve; pyridinium p-toluenesulfonate; Dess-Martin periodane; hydroquinone; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In diethyl ether; dichloromethane; tert-butyl alcohol; benzene;
DOI:10.1016/j.tet.2006.06.046