trans-chloro-[5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethyl(zinc)porphyrin]bis(triethylphenyl)platinum(II)

Base Information

Chemical Name:trans-chloro-[5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethyl(zinc)porphyrin]bis(triethylphenyl)platinum(II)
CAS No.:1182371-12-5
Molecular Formula:C₅₀H₆₅ClN₄P₂PtZn
Molecular Weight:1079.96
Hs Code.:

Synonyms:trans-chloro-[5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethyl(zinc)porphyrin]bis(triethylphenyl)platinum(II)

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Chemical Property of trans-chloro-[5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethyl(zinc)porphyrin]bis(triethylphenyl)platinum(II)

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Technology Process of trans-chloro-[5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethyl(zinc)porphyrin]bis(triethylphenyl)platinum(II)

There total 2 articles about trans-chloro-[5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethyl(zinc)porphyrin]bis(triethylphenyl)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 14177-93-6,15692-07-6,13965-02-1
trans-platinum(triethylphosphine)₂(chloro)₂

: 1182371-21-6
5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethylporphyrinato zinc(II)

: 1182371-12-5
trans-chloro-[5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethyl(zinc)porphyrin]bis(triethylphenyl)platinum(II)

Guidance literature:: With CuI; In dichloromethane; (Ar); Schlenk technique; CuI was added to mixt. of Pt complex (5 equiv.)and Zn complex in CH2Cl2/(i-Pr)2NH (1/1); stirred under reflux overnigh t; evapd. (vac.); redissolved in CH2Cl2; washed (H2O); dried (K2CO3); evapd.; dissolved in CH2Cl2; chromd. (hexane/CH2Cl2, 40/60); elem. anal.;
DOI:10.1021/ic900840w

Reference yield:

: 5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin

: 1182371-12-5
trans-chloro-[5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethyl(zinc)porphyrin]bis(triethylphenyl)platinum(II)

Guidance literature:: Multi-step reaction with 3 steps

1: CH₃ONa / chloroform; methanol

2: Bu₄NF / tetrahydrofuran

3: CuI / dichloromethane

With CH₃ONa; Bu₄NF; CuI; In tetrahydrofuran; methanol; dichloromethane; chloroform;
DOI:10.1021/ic900840w

Reference yield: 60.0%

: 1182371-12-5
trans-chloro-[5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethyl(zinc)porphyrin]bis(triethylphenyl)platinum(II)

: 536-74-3
phenylacetylene

: 1182371-14-7
trans-(ethynylphenyl)[5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethyl(zinc)porphyrin]bis(triethylphenyl)platinum(II)

Guidance literature:: With CuI; In dichloromethane; (Ar); Schlenk technique; CuI was added to mixt. of Pt complex and C6H5CCH in CH2Cl2/(i-Pr)2NH (1/1); stirred under reflux overnight; evapd. (vac.); redissolved in CH2Cl2; washed (H2O); dried (K2CO3); evapd.; dissolved in CH2Cl2; chromd. (hexane/CH2Cl2, 40/60); elem. anal.;
DOI:10.1021/ic900840w