5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethylporphyrinato zinc(II)

Base Information

Chemical Name:5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethylporphyrinato zinc(II)
CAS No.:1182371-21-6
Molecular Formula:C₃₈H₃₆N₄Zn
Molecular Weight:614.121
Hs Code.:

Synonyms:5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethylporphyrinato zinc(II)

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Chemical Property of 5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethylporphyrinato zinc(II)

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Technology Process of 5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethylporphyrinato zinc(II)

There total 2 articles about 5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethylporphyrinato zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 1182371-09-0
5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin zinc

: 1182371-21-6
5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethylporphyrinato zinc(II)

Guidance literature:: With Bu₄NF; In tetrahydrofuran; (Ar); Schlenk technique; soln. of Bu4NF in THF was added to soln. of Zn complex in THF; stirred at room temp. for 12 h; evapd. (vac.); dissolved in CH2Cl2; washed (satd. NH4Cl, H2O); dried (MgSO4); chromd. (silica, CH2Cl2);
DOI:10.1021/ic900840w

Reference yield:

: 5-[4-(trimethylsilyl)ethynylphenyl]-13,17-diethyl-2,3,7,8,12,18-hexamethyl-porphyrin

: 1182371-21-6
5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethylporphyrinato zinc(II)

Guidance literature:: Multi-step reaction with 2 steps

1: CH₃ONa / chloroform; methanol

2: Bu₄NF / tetrahydrofuran

With CH₃ONa; Bu₄NF; In tetrahydrofuran; methanol; chloroform;
DOI:10.1021/ic900840w

Reference yield: 72.0%

: 61250-65-5
dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I)

: 1182371-21-6
5-(4-ethynylphenyl)-13,17-diethyl-2,3,7,8,12,18-hexamethylporphyrinato zinc(II)

: bis[5-(4-ethynylbenzene)-13,17-diethyl-2,3,7,8,12,18-hexamethylzinc(II)-porphyrin]bis(bis(diphenylphosphino)methane)diplatinum(I)

Guidance literature:: With sodium methoxide; In tetrahydrofuran; methanol; (Ar); using Schlenk techniques; dissolving of (5-(4-CCPh)-13,17-diethyl-2,3,7,8,12,18-hexamethyl)Zn pophyrin (2 equiv.) in THF; addn. of excess of NaOMe in MeOH; stirring for 0.5 h; addn. of soln. of Pt2(dppm)2Cl2 (1equiv.) in MeOH; reflux overnight; pptn., filtration, washing with cold MeOH; drying on vac. pump overnight; elem. anal.;
DOI:10.1021/om900584n