(4R)-4-(phenylmethyl)-3-<2,4,6-trideoxy-2,4-dimethyl-7,8-O-(1-methylethylidene)-5-O-(phenylmethyl)-D-glycero-D-gluco-octanoyl>-2-oxazolidinone

Base Information

Chemical Name:(4R)-4-(phenylmethyl)-3-<2,4,6-trideoxy-2,4-dimethyl-7,8-O-(1-methylethylidene)-5-O-(phenylmethyl)-D-glycero-D-gluco-octanoyl>-2-oxazolidinone
CAS No.:221007-83-6
Molecular Formula:C₃₀H₃₉NO₇
Molecular Weight:525.642
Hs Code.:

Synonyms:(4R)-4-(phenylmethyl)-3-<2,4,6-trideoxy-2,4-dimethyl-7,8-O-(1-methylethylidene)-5-O-(phenylmethyl)-D-glycero-D-gluco-octanoyl>-2-oxazolidinone

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Chemical Property of (4R)-4-(phenylmethyl)-3-<2,4,6-trideoxy-2,4-dimethyl-7,8-O-(1-methylethylidene)-5-O-(phenylmethyl)-D-glycero-D-gluco-octanoyl>-2-oxazolidinone

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Technology Process of (4R)-4-(phenylmethyl)-3-<2,4,6-trideoxy-2,4-dimethyl-7,8-O-(1-methylethylidene)-5-O-(phenylmethyl)-D-glycero-D-gluco-octanoyl>-2-oxazolidinone

There total 5 articles about (4R)-4-(phenylmethyl)-3-<2,4,6-trideoxy-2,4-dimethyl-7,8-O-(1-methylethylidene)-5-O-(phenylmethyl)-D-glycero-D-gluco-octanoyl>-2-oxazolidinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 101711-78-8,131685-53-5
(3R)-3-propionyl-4-benzyloxazolidin-2-one

: 221007-82-5
(2R,3R)-3-Benzyloxy-4-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-butyraldehyde

: 221007-83-6
(4R)-4-(phenylmethyl)-3-<2,4,6-trideoxy-2,4-dimethyl-7,8-O-(1-methylethylidene)-5-O-(phenylmethyl)-D-glycero-D-gluco-octanoyl>-2-oxazolidinone

Guidance literature:: With di-n-butylboryl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine; In dichloromethane; at -78 - 0 ℃;
DOI:10.1021/jo981310r

Reference yield:

: 32233-43-5
2-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethanol

: 221007-83-6
(4R)-4-(phenylmethyl)-3-<2,4,6-trideoxy-2,4-dimethyl-7,8-O-(1-methylethylidene)-5-O-(phenylmethyl)-D-glycero-D-gluco-octanoyl>-2-oxazolidinone

Guidance literature:: Multi-step reaction with 5 steps

1: (COCl)2, DMSO, Et₃N / CH₂Cl₂ / -78 °C

2: 4 Angstroem molecular sieves / toluene / -78 °C

3: 83 percent / NaH, Bu₄NI / tetrahydrofuran; dimethylformamide / 3 h / 23 °C

4: 1.) O₃, Sudan Red, 2.) Ph₃P / CH₂Cl₂ / -78 - 22 °C

5: 9.30 g / Bu₂BOTf, i-Pr₂NEt / CH₂Cl₂ / -78 - 0 °C

With oxalyl dichloride; 4 A molecular sieve; sudan red; di-n-butylboryl trifluoromethanesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; ozone; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; triphenylphosphine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo981310r

Reference yield:

: 32233-44-6
2-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]acetaldehyde

: 221007-83-6
(4R)-4-(phenylmethyl)-3-<2,4,6-trideoxy-2,4-dimethyl-7,8-O-(1-methylethylidene)-5-O-(phenylmethyl)-D-glycero-D-gluco-octanoyl>-2-oxazolidinone

Guidance literature:: Multi-step reaction with 4 steps

1: 4 Angstroem molecular sieves / toluene / -78 °C

2: 83 percent / NaH, Bu₄NI / tetrahydrofuran; dimethylformamide / 3 h / 23 °C

3: 1.) O₃, Sudan Red, 2.) Ph₃P / CH₂Cl₂ / -78 - 22 °C

4: 9.30 g / Bu₂BOTf, i-Pr₂NEt / CH₂Cl₂ / -78 - 0 °C

With 4 A molecular sieve; sudan red; di-n-butylboryl trifluoromethanesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; ozone; N-ethyl-N,N-diisopropylamine; triphenylphosphine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo981310r