methyl 4-((tert-butyldimethylsiloxy)methyl)-2,2-bis(4-chlorophenyl)-4-pentenoate

Base Information

Chemical Name:methyl 4-((tert-butyldimethylsiloxy)methyl)-2,2-bis(4-chlorophenyl)-4-pentenoate
CAS No.:1306830-25-0
Molecular Formula:C₂₅H₃₂Cl₂O₃Si
Molecular Weight:479.519
Hs Code.:

Synonyms:methyl 4-((tert-butyldimethylsiloxy)methyl)-2,2-bis(4-chlorophenyl)-4-pentenoate

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Chemical Property of methyl 4-((tert-butyldimethylsiloxy)methyl)-2,2-bis(4-chlorophenyl)-4-pentenoate

Chemical Property:

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Technology Process of methyl 4-((tert-butyldimethylsiloxy)methyl)-2,2-bis(4-chlorophenyl)-4-pentenoate

There total 1 articles about methyl 4-((tert-butyldimethylsiloxy)methyl)-2,2-bis(4-chlorophenyl)-4-pentenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 5359-38-6
methyl 2,2-bis(4-chlorophenyl) acetate

: 491879-65-3
methanesulfonic acid 2-(tert-butyl-dimethyl-silanyloxymethyl)allyl ester

: 1306830-25-0
methyl 4-((tert-butyldimethylsiloxy)methyl)-2,2-bis(4-chlorophenyl)-4-pentenoate

Guidance literature:: methyl 2,2-bis(4-chlorophenyl) acetate; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; for 0.416667h;

methanesulfonic acid 2-(tert-butyl-dimethyl-silanyloxymethyl)allyl ester; In tetrahydrofuran; mineral oil; at 20 - 40 ℃; for 20.67h;
DOI:10.1021/jo2006158

Reference yield: 52.0%

: 1306830-25-0
methyl 4-((tert-butyldimethylsiloxy)methyl)-2,2-bis(4-chlorophenyl)-4-pentenoate

: 1306830-26-1
α,α-bis(4-chlorophenyl)-γ-methylidene-δ-valerolactone

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at -65 - 0 ℃; for 5h;
DOI:10.1021/jo2006158

Reference yield:

: 1306830-25-0
methyl 4-((tert-butyldimethylsiloxy)methyl)-2,2-bis(4-chlorophenyl)-4-pentenoate

: 1306830-33-0
C₂₇H₂₅Cl₂NO₄S

Guidance literature:: Multi-step reaction with 2 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran / 5 h / -65 - 0 °C

2: allyl(cyclopentadiene)palladium(II); O,O'-(1,1'-biphenyl-2,2'-diyl)-N,N'-diisopropylphosphoramidite / toluene / 24 h / 80 °C

With allyl(cyclopentadiene)palladium(II); tetrabutyl ammonium fluoride; O,O'-(1,1'-biphenyl-2,2'-diyl)-N,N'-diisopropylphosphoramidite; In tetrahydrofuran; toluene;
DOI:10.1021/jo2006158