5359-38-6

Basic information

• Product Name: DDA-P,P'' METHYL ESTER)
• Synonyms: DDA-P,P'' METHYL ESTER);bis(4-chlorophenyl)acetic acid, methyl ester;4-Chloro-α-(4-chlorophenyl)benzeneacetic acid methyl ester;Bis(p-chlorophenyl)acetic acid methyl ester;DDA methyl ester;p,p'-DDA methyl ester
• CAS NO: 5359-38-6
• Molecular Formula: C₁₅H₁₂Cl₂O₂
• Molecular Weight: 295.16058
• Mol File: 5359-38-6.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 386.4°Cat760mmHg
• Flash Point: 149.7°C
• Appearance: /
• Density: 1.283g/cm³
• Vapor Pressure: 3.56E-06mmHg at 25°C
• Refractive Index: 1.578
• CAS DataBase Reference: DDA-P,P'' METHYL ESTER)(CAS DataBase Reference)
• NIST Chemistry Reference: DDA-P,P'' METHYL ESTER)(5359-38-6)
• EPA Substance Registry System: DDA-P,P'' METHYL ESTER)(5359-38-6)

Safety Data

• Hazardous Substances Data: 5359-38-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H12Cl2O2/c1-19-15(18)14(10-2-6-12(16)7-3-10)11-4-8-13(17)9-5-11/h2-9,14H,1H3

Upstream product

• 67-56-1 methanol 
• 50-29-3 p,p'-DDT 
• 83-05-6 bis(4'-chlorophenyl)acetic acid 
• 361-07-9 1,1,1-trifluoro-2,2-bis(p-chlorophenyl)ethane 
• 124-41-4 sodium methylate 

Downstream Products

• 1384881-82-6 2,2-bis(4-chlorophenyl)pent-4-en-1-ol 
• 1306830-25-0 methyl 4-((tert-butyldimethylsiloxy)methyl)-2,2-bis(4-chlorophenyl)-4-pentenoate 
• 1306830-33-0 C₂₇H₂₅Cl₂NO₄S 
• 1306830-26-1 α,α-bis(4-chlorophenyl)-γ-methylidene-δ-valerolactone 
• 405551-72-6 2,2-bis-(4-chloro-phenyl)-propionic acid methyl ester 

Relevant articles and documents

Aerobic Electrochemical Transformations of DDT to Oxygen-Incorporated Products Catalyzed by a B12 Derivative

Electrochemical transformations of DDT into oxygen-incorporated products, amides and esters, catalyzed by a B12 derivative, heptamethyl cobyrinate perchlorate, have been developed under aerobic conditions. The dechlorinative oxygenation of DDT forms the acyl chloride as an intermediate for the synthesis of the amide and ester in the reaction with the amine and alcohol, respectively. This electrochemical method demonstrated with 20 oxygen-incorporated dechlorinated products up to 88% yields with 15 new compounds and was also successfully applied to the conversion of methoxychlor to an amide and ester.

Synthesis of a B12-BODIPY dyad for B12-inspired photochemical transformations of a trichloromethylated organic compound

A B12complex-BODIPY dyad was synthesized by peripheral modification of cobalamin derivatives. The photophysical properties of the dyad were investigated by UV-vis, PL, and transient absorption spectroscopy. A visible light-driven dechlorination reaction of a trichlorinated organic compound, DDT, was reported. The dyad showed efficient catalysis for dechlorination under N2with turnover numbers of over 220 for the reaction. One-pot syntheses of an ester and amide from DDT and benzotrichloride were also achieved using the dyad under air.

Synthesis of nine-membered azlactones by palladium-catalyzed ring-expansion of γ-methylidene-δ-valerolactones with aziridines

A palladium-catalyzed formal [6 + 3] cyclization of γ-methylidene- δ-valerolactones with aziridines has been developed to produce 1,4-oxazonan-9-ones, a class of nine-membered azlactones that are not easily accessible by existing methods. The products thus obtained can also be further functionalized with ease.