dimethylsulfonium (1-benzoyl-1-methacryloylcarbamoyl)methylide

Base Information

• Chemical Name: dimethylsulfonium (1-benzoyl-1-methacryloylcarbamoyl)methylide
• CAS No.: 351530-22-8
• Molecular Formula: C₁₅H₁₇NO₃S
• Molecular Weight: 291.371
• Mol file: 351530-22-8.mol

Synonyms:dimethylsulfonium (1-benzoyl-1-methacryloylcarbamoyl)methylide

Chemical Property of dimethylsulfonium (1-benzoyl-1-methacryloylcarbamoyl)methylide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of dimethylsulfonium (1-benzoyl-1-methacryloylcarbamoyl)methylide

There total 1 articles about dimethylsulfonium (1-benzoyl-1-methacryloylcarbamoyl)methylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

methacryloyl isocyanate (4474-60-6) + (benzoylmethylene)dimethylsulfurane (5633-34-1) → dimethylsulfonium (1-benzoyl-1-methacryloylcarbamoyl)methylide (351530-22-8)

Guidance literature:

In benzene; at 20 ℃; for 8h;

DOI:10.1080/00304940109356584

Reference yield: 6.0%

dimethylsulfonium (1-benzoyl-1-methacryloylcarbamoyl)methylide (351530-22-8) → r-2-benzoyl-t-1-cyano-1-methylcyclopropane (73178-39-9) + r-2-benzoyl-t-1-carbamoyl-1-methylcyclopropane

Guidance literature:

With copper(II) sulfate; In xylene; for 2h; Heating;

DOI:10.1080/00304940109356584

Reference yield:

dimethylsulfonium (1-benzoyl-1-methacryloylcarbamoyl)methylide (351530-22-8) → r-2-benzoyl-t-1-cyano-1-methylcyclopropane (73178-39-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 39 percent / CuSO₄ / xylene / 2 h / Heating

2: 17 percent / CuSO₄ / xylene / 10 h / Heating

With copper(II) sulfate; In xylene;

DOI:10.1080/00304940109356584

upstream raw materials:

methacryloyl isocyanate

(benzoylmethylene)dimethylsulfurane

Downstream raw materials:

r-2-benzoyl-t-1-cyano-1-methylcyclopropane