4474-60-6Relevant academic research and scientific papers
Method of preparing acylisocyanates
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, (2008/06/13)
The invention relates to a novel process for the preparation of acyl isocyanates which consists in reacting oxalyl chloride with an N-trialkylsilylcarboxamide or an N,N-bis(trialkylsilyl)carboxamide. The process makes it possible to obtain acyl isocyanates in good yield, in particular acyl isocyanates derived from aliphatic amides, and under simplified reaction conditions.
Process for the preparation of acyl isocyanates
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, (2008/06/13)
The invention concerns a process for the preparation of acyl isocyanates which consists of reacting oxalyl chloride with a salt selected from the group consisting of hydrohalides and sulphates of carboxamides and/or carbamates, unsubstituted on nitrogen, then heating the reaction mixture at a temperature between 30° and 150° C. The process is suitable for preparation of acyl isocyanates with excellent yields in easy to control operational conditions.
Production of isocyanate compounds
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, (2008/06/13)
Production of an alkenoyl isocyanate of the formula: STR1 wherein R is a hydrogen atom or a lower alkyl group by reacting an acrylamide of the formula: STR2 wherein R is as defined above with an oxalyl halide of the formula(COX) 2wherein X is a halogen at
Preparation of alkenoyl isocyanates
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, (2008/06/13)
A process for preparing alkenoyl isocyanates of the formula: STR1 wherein R is a hydrogen atom or a lower alkyl group which comprises subjecting an oxazolinedione hydrohalide of the formula: STR2 wherein X is a halogen atom and R is as defined above to decomposition under an ordinary pressure, in the presence of a hydrogen halide-eliminating agent and/or in a liquid medium having a dielectric constant of not more than 4.
