bis(triphenylphosphine)(η²-2-(diazo(phenyl)methyl)phenyl-4-nitrocinnamate)platinum(0)

Base Information

• Chemical Name: bis(triphenylphosphine)(η²-2-(diazo(phenyl)methyl)phenyl-4-nitrocinnamate)platinum(0)
• CAS No.: 1448998-02-4
• Molecular Formula: C₅₈H₄₅N₃O₄P₂Pt
• Molecular Weight: 1105.04

Synonyms:bis(triphenylphosphine)(η²-2-(diazo(phenyl)methyl)phenyl-4-nitrocinnamate)platinum(0)

Chemical Property of bis(triphenylphosphine)(η²-2-(diazo(phenyl)methyl)phenyl-4-nitrocinnamate)platinum(0)

Chemical Property:

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Technology Process of bis(triphenylphosphine)(η²-2-(diazo(phenyl)methyl)phenyl-4-nitrocinnamate)platinum(0)

There total 5 articles about bis(triphenylphosphine)(η²-2-(diazo(phenyl)methyl)phenyl-4-nitrocinnamate)platinum(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) + 2-[diazo(phenyl)methyl]phenyl cinnamate → bis(triphenylphosphine)(η2-2-(diazo(phenyl)methyl)phenyl-4-nitrocinnamate)platinum(0) (1448998-02-4)

Guidance literature:

In benzene; for 1h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1016/j.jorganchem.2013.04.045

Reference yield:

C22H15NO5 + [(PPh3)2PtH(SiHPh2)] (40869-79-2) → bis(triphenylphosphine)(η2-2-(diazo(phenyl)methyl)phenyl-4-nitrocinnamate)platinum(0) (1448998-02-4) + diphenylsilane (775-12-2)

Guidance literature:

Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1016/j.jorganchem.2013.04.045

Reference yield:

2-Hydroxybenzophenone (117-99-7) → bis(triphenylphosphine)(η2-2-(diazo(phenyl)methyl)phenyl-4-nitrocinnamate)platinum(0) (1448998-02-4)

Guidance literature:

Multi-step reaction with 4 steps

1.1: pyridine / 100 °C / Inert atmosphere; Schlenk technique; Glovebox

2.1: toluene-4-sulfonic acid / toluene / Inert atmosphere; Schlenk technique; Glovebox; Reflux

3.1: sodium hydride / tetrahydrofuran / 0 °C / Inert atmosphere; Schlenk technique; Glovebox

3.2: Inert atmosphere; Glovebox; Schlenk technique; Reflux

4.1: benzene / 1 h / Inert atmosphere; Schlenk technique; Glovebox

With pyridine; sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; toluene; benzene;

DOI:10.1016/j.jorganchem.2013.04.045

upstream raw materials:

2-Hydroxybenzophenone

ethylenebis(triphenylphosphine)platinum⁽⁰⁾

[(PPh₃)₂PtH(SiHPh₂)]

Downstream raw materials:

[(PPh₃)₂PtH(SiHPh₂)]

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