117-99-7

Usage

Uses

Used in Plastics Industry:
2-Hydroxybenzophenone is used as a UV absorber in plastics to protect them from the harmful effects of ultraviolet radiation, thereby enhancing their durability and longevity.
Used in Chemical Research:
2-Hydroxybenzophenone is used to quantify the metabolites of unmethylated extracts from the supernatants of Pseudomonas acidovorans cultures grown on 1,1-diphenylethylene. This application is crucial for studying the metabolic processes and interactions of these bacteria with their environment.
Used in Polymer Synthesis:
2-Hydroxybenzophenone is used as a monomer to form copolymers, such as 2-hydroxy, 3-allyl, 4,4′-dimethoxybenzophenone, with methyl methacrylate. These copolymers have potential applications in various industries, including coatings, adhesives, and composite materials.
Used in Photostabilizer Production:
2-Hydroxybenzophenone is used in the formation of photostabilizer compounds with 2,2,6,6-tetramethylpiperidine under phase transfer catalysis conditions. These photostabilizers are important for protecting materials from the degrading effects of light exposure.
Used in Organic Synthesis:
2-Hydroxybenzophenone reacts with 3-aminophenyl boronic acid to form macrocyclic boronates, which have potential applications in various fields, such as pharmaceuticals, materials science, and supramolecular chemistry.

Preparation

Preparation by Friedel–Crafts acylation of benzene in the presence of aluminium chloride, ? with 2-hydroxybenzoyl chloride (salicylic acid chloride), (52%), (39%), at temperature <60°; ? with o-anisoyl chloride. Demethylation occurred during the Friedel–Crafts acylation, especially in the presence of ferric chloride at 130–140°; ? with 2-ethoxybenzoyl chloride in a boiling water bath (42%).

Synthesis Reference(s)

Journal of the American Chemical Society, 76, p. 5469, 1954 DOI: 10.1021/ja01650a062The Journal of Organic Chemistry, 32, p. 3844, 1967 DOI: 10.1021/jo01287a027

InChI:InChI=1/C13H10O2/c14-12-9-5-4-8-11(12)13(15)10-6-2-1-3-7-10/h1-9,14H

Upstream product

• 85-19-8 (5-chloro-2-hydroxyphenyl)phenylmethanone 
• 119-61-9 benzophenone 
• 93-99-2 benzoic acid phenyl ester 
• 100-52-7 benzaldehyde 
• 15086-27-8 aluminium(III) phenoxide 
• 98-88-4 benzoyl chloride 
• 98-95-3 nitrobenzene 
• 139-02-6 sodium phenoxide 
• 98-07-7 Benzotrichlorid 
• 21615-34-9 2-Methoxybenzoyl chloride 
• 71-43-2 benzene 
• 65-85-0 benzoic acid 
• 108-95-2 phenol 
• 2835-77-0 (2-aminophenyl)(phenyl)methanone 

Downstream Products

• 2553-04-0 ortho-methoxybenzophenone 
• 810672-90-3 o-butoxybenzophenone 
• 127154-52-3 (2-ethoxyphenyl)(phenyl)methanone 
• 860564-37-0 2-heptyloxy-benzophenone 
• 187093-06-7 2-isobutoxybenzophenone 
• 90-47-1 xanth-9-one 
• 833-50-1 2-phenylbenzo[d]oxazole 
• 26094-08-6 2-hydroxybenzophenone oxime 
• 81118-45-8 o-hydroxythiobenzophenone 
• 59986-61-7 (Z)-o-hydroxybenzophenone oxime 
• 59986-60-6 (E)-o-hydroxybenzophenone oxime 
• 93254-81-0 o-(benzyloxy)benzophenone 
• 29909-72-6 3-Phenylbenzofuran 
• 60312-24-5 PL-158 

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NoteSynthesis, spectroscopic characterization and structural studies of mixed ligand complexes of Sr(II) and Ba(II) with 2-Hydroxybenzophenone (cas 117-99-7) and salicylaldehyde, hydroxyaromatic ketones or β-diketones: Crystal structure of 2-HOC6H4C(O)C6H509/04/2019

Reactions of Sr(II) and Ba(II) chlorides with 2-hydroxybenzophenone and salicylaldehyde, hydroxyaromatic ketones or β-diketones in 1:1:1 molar ratios have resulted in the formation of mixed ligand complexes of the type [MLL′(H2O)2] (M = Sr(II) or Ba(II); HL = 2-hydroxybenzophenone and HL′ = s...detailed

2-Hydroxybenzophenone (cas 117-99-7) UV-absorbers containing 2,2,6,6-tetramethylpiperidine (HALS) group — benzoylation of corresponding phenol derivatives09/02/2019

Phenol derivatives containing 2,2,6,6-tetramethylpiperidine group were successfully benzoylated with both benzoyl chloride in the presence of aluminium chloride and benzotrichloride in aqueous sodium hydroxide solution. The 2-hydroxybenzophenone UV-absorbers bearing light stabilizing fragment —...detailed

2-Hydroxybenzophenone (cas 117-99-7) UV-absorber containing 4,4,5,5-tetramethylimidazolidine fragment08/30/2019

2-Hydroxy-4-[(2,4,4,5,5-pentamethylimidazolidin-2-yl)methoxy]benzophenone (4)-2-hydroxybenzophenone UV-absorber containing 4,4,5,5-tetramethylimidazolidine fragment was obtained in the reaction of 4-(2-oxopropoxy)-2-hydroxybenzophenone (3) with 2,3-diamino-2,3-dimethylbutane (2).detailed

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First direct access to 2-hydroxybenzophenones via nickel-catalyzed cross-coupling of 2-hydroxybenzaldehydes with aryl iodides

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PdCl2/DABCO-catalyzed direct arylation of 2-hydroxybenzaldehydes in H2O

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AN INTRAMOLECULAR OXENOID OXIDATION

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