(6RS)-(Z)-trifluoromethanesulfonic acid 6-(3-pentenyl-5-trimethylsilyl)-1-cyclohexenyl ester

Base Information

Chemical Name:(6RS)-(Z)-trifluoromethanesulfonic acid 6-(3-pentenyl-5-trimethylsilyl)-1-cyclohexenyl ester
CAS No.:279248-48-5
Molecular Formula:C₁₅H₂₅F₃O₃SSi
Molecular Weight:370.508
Hs Code.:

Synonyms:(6RS)-(Z)-trifluoromethanesulfonic acid 6-(3-pentenyl-5-trimethylsilyl)-1-cyclohexenyl ester

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Chemical Property of (6RS)-(Z)-trifluoromethanesulfonic acid 6-(3-pentenyl-5-trimethylsilyl)-1-cyclohexenyl ester

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Technology Process of (6RS)-(Z)-trifluoromethanesulfonic acid 6-(3-pentenyl-5-trimethylsilyl)-1-cyclohexenyl ester

There total 3 articles about (6RS)-(Z)-trifluoromethanesulfonic acid 6-(3-pentenyl-5-trimethylsilyl)-1-cyclohexenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 37595-74-7
N,N-phenylbistrifluoromethane-sulfonimide

: 279248-52-1
(2RS)-(Z)-2-(3-pentenyl-5-trimethylsilyl)cyclohexanone

: 279248-48-5
(6RS)-(Z)-trifluoromethanesulfonic acid 6-(3-pentenyl-5-trimethylsilyl)-1-cyclohexenyl ester

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 - 0 ℃; for 15h;
DOI:10.1002/(SICI)1099-0690(200005)2000:10<1959::AID-EJOC1959>3.0.CO;2-R

Reference yield:

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 279248-48-5
(6RS)-(Z)-trifluoromethanesulfonic acid 6-(3-pentenyl-5-trimethylsilyl)-1-cyclohexenyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 35 percent / KN(SiMe₃)2 / tetrahydrofuran / 4 h / -78 - 20 °C

2: 79 percent / LDA / tetrahydrofuran; hexane / 15 h / -78 - 0 °C

With potassium hexamethylsilazane; lithium diisopropyl amide; In tetrahydrofuran; hexane; 1: Alkylation / 2: Esterification;
DOI:10.1002/(SICI)1099-0690(200005)2000:10<1959::AID-EJOC1959>3.0.CO;2-R

Reference yield:

: 120950-81-4
1-iodo-5-trimethylsilyl-3-pentene

: 279248-48-5
(6RS)-(Z)-trifluoromethanesulfonic acid 6-(3-pentenyl-5-trimethylsilyl)-1-cyclohexenyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 35 percent / KN(SiMe₃)2 / tetrahydrofuran / 4 h / -78 - 20 °C

2: 79 percent / LDA / tetrahydrofuran; hexane / 15 h / -78 - 0 °C

With potassium hexamethylsilazane; lithium diisopropyl amide; In tetrahydrofuran; hexane; 1: Alkylation / 2: Esterification;
DOI:10.1002/(SICI)1099-0690(200005)2000:10<1959::AID-EJOC1959>3.0.CO;2-R